Cavity-Tailored, Self-Sorting Supramolecular Catalytic Boxes for Selective Oxidation

Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by solution X-ray scattering in conjuncti...

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 130; no. 50; pp. 16828 - 16829
Main Authors Lee, Suk Joong, Cho, So-Hye, Mulfort, Karen L, Tiede, David M, Hupp, Joseph T, Nguyen, SonBinh T
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 17.12.2008
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
STRUCTURAL-CHARACTERIZATION
CHIRAL MOLECULAR SQUARE
ACID
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Summary:Using a steric self-sorting strategy, the assembly of highly ordered and rigid supramolecular boxes possessing catalytic properties has been achieved in one step. The formation of these assemblies, comprising up to 18 porphyrin centers, was readily confirmed by solution X-ray scattering in conjunction with fluorescent spectroscopy. Size-selective and enantioselective oxidation catalysis were both demonstrated.
Bibliography:Complete experimental details of syntheses, compound characterization, and X-ray experimental methods and data analysis. This material is available free of charge via the Internet at http://pubs.acs.org.
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content type line 23
ISSN:0002-7863
1520-5126
DOI:10.1021/ja804014y