A Simple Method for Controlling Dendritic Architecture and Diversity:  A Parallel Monomer Combination Approach

A novel parallel monomer combination approach to manipulating the architectural disposition of dendritic macromolecules is described. It harnesses the synthetic speed and power of the double-stage convergent growth approach and classical parallel synthesis to prepare diverse series of dendrimers tha...

Full description

Saved in:
Bibliographic Details
Published inJournal of organic chemistry Vol. 65; no. 22; pp. 7612 - 7617
Main Authors Freeman, Adam W, Chrisstoffels, Lysander A. J, Fréchet, Jean M. J
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 03.11.2000
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
NANOCLUSTERS
POLYESTERS
CATALYSIS
BLOCK-COPOLYMERS
MACROMOLECULES
CONVERGENT APPROACH
MOLECULAR ARCHITECTURE
GROWTH
CHEMISTRY
DENDRIMERS
Online AccessGet full text

Cover

More Information
Summary:A novel parallel monomer combination approach to manipulating the architectural disposition of dendritic macromolecules is described. It harnesses the synthetic speed and power of the double-stage convergent growth approach and classical parallel synthesis to prepare diverse series of dendrimers that possess a predetermined number and arrangement of “internal” functional moieties. This methodology is applied for the preparation of a novel family of poly(benzyl ether) dendrimers possessing 1−15 “internal” allyloxy groups, which are displayed in a highly controlled, layer-specific, generational manner.
Bibliography:istex:65B4CF6EA9853DB1903A6FECDCAEC6C9690DAC6D
ark:/67375/TPS-3TNG40BW-B
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0022-3263
1520-6904
DOI:10.1021/jo005592i