Effect of Ring Substitution Position on the Structural Conformation of Mercaptobenzoic Acid Self-Assembled Monolayers on Au(111)

• Published in: Langmuir Vol. 22; no. 26; pp. 11134 - 11141
• Main Authors: Lee, Jonathan R. I, Willey, Trevor M, Nilsson, Joakim, Terminello, Louis J, De Yoreo, James J, van Buuren, Tony
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 19.12.2006
• Subjects: Chemistry; Exact sciences and technology; General and physical chemistry; Self assembly; Monolayer; Film; Hydrogen; Alcohol; Isomer; Fine structure; Synthesis; Substitution; Carboxylic acid; Alkanol; Carboxyl group; Monomer; Sulfur; Thiol; Ethanol; Contact angle; Orientation; Carbon; Bilayer; Substrate; Morphology; Preparation; Aryl; Acetic acid; X ray absorption; Conformation
• ISSN: 0743-7463; 1520-5827
• DOI: 10.1021/la0611256

Near-edge X-ray absorption fine structure (NEXAFS) spectroscopy, photoemission spectroscopy (PES), and contact angle measurements have been used to examine the structure and bonding of self-assembled monolayers (SAMs) prepared on Au(111) from the positional isomers of mercaptobenzoic acid (MBA). The isomer of MBA and solvent chosen in SAM preparation has considerable bearing upon film morphology. Carbon K-edge NEXAFS measurements indicate that the monomers of 2-, 3-, and 4-MBA have well-defined orientations within their respective SAMs. Monomers of 3- and 4-MBA assume an upright orientation on the Au substrates in monolayers prepared using an acetic acid in ethanol solvent. The aryl ring and carboxyl group of these molecules are tilted from the surface normal by a colatitudal angle of ∼30°. Preparation of 4-MBA SAMs using pure ethanol solvent, a more traditional means of synthesis, had no appreciable effect upon the monomer orientation. Nonetheless, S(2p) PES measurements illustrate that it results in extensive bilayer formation via carboxyl group hydrogen-bonding between 4-MBA monomers. In 2-MBA monolayers prepared using acetic acid/ethanol solvent, the monomers adopt a more prostrate orientation on the Au substrates, in which the aryl ring and carboxyl group of the molecules are tilted ∼50° from the surface normal. This configuration is consistent with an interaction between both the mercaptan sulfur and carboxyl group of 2-MBA with the underlying substrate. S(2p) and C(1s) PES experiments provide supporting evidence for a bidentate interaction between 2-MBA and Au(111).