Structural and Magnetic Properties of a Novel Ferrocenyl−Diiodine Charge Transfer Complex

The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented “double” charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.

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Bibliographic Details
Published inInorganic chemistry Vol. 42; no. 13; pp. 3975 - 3977
Main Authors Allen, David W, Berridge, Rory, Bricklebank, Neil, Forder, Susan D, Palacio, Fernando, Coles, Simon J, Hursthouse, Michael B, Skabara, Peter J
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 30.06.2003
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Summary:The reaction of 4-ferrocenyl-1,3-dithiole-2-thione with diiodine affords an unprecedented “double” charge-transfer complex; the highly ordered ferrocenium units are held by a supramolecular polyiodide chain, and the material shows evidence of the formation of zigzag magnetic chains below 2 K.
Bibliography:istex:71C8FAAC90791CE89D99BCF4EB89361AA822C9A5
ark:/67375/TPS-M3081JZT-N
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0020-1669
1520-510X
DOI:10.1021/ic034092f