Atom Transfer Radical Polymerization Enabled by Sonochemically Labile Cu-carbonate Species

Atom transfer radical polymerization (ATRP) has been previously mediated by ultrasound using a low concentration of copper complex in water (sono-ATRP) or by addition of piezoelectric materials in organic solvents (mechano-ATRP). However, these procedures proceeded slowly and yielded polymers contam...

Full description

Saved in:
Bibliographic Details
Published inACS macro letters Vol. 8; no. 2; pp. 161 - 165
Main Authors Wang, Zhenhua, Lorandi, Francesca, Fantin, Marco, Wang, Zongyu, Yan, Jiajun, Wang, Zhanhua, Xia, Hesheng, Matyjaszewski, Krzysztof
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 19.02.2019
Online AccessGet full text

Cover

Abstract Atom transfer radical polymerization (ATRP) has been previously mediated by ultrasound using a low concentration of copper complex in water (sono-ATRP) or by addition of piezoelectric materials in organic solvents (mechano-ATRP). However, these procedures proceeded slowly and yielded polymers contaminated by new chains initiated by hydroxyl radicals or by residual piezoelectrics. Unexpectedly, in the presence of sodium carbonate, rapid sono-ATRP of methyl acrylate in DMSO was achieved (80% conversion in <2 h) with excellent control of molecular weights and low dispersities (M w/M n < 1.2). The in situ formed CuII/L-CO3 complex in the the presence of ultrasound generated CuI/L species as activators for ATRP and carbonate radical anions. The latter were scavenged by DMSO that was oxidized to dimethyl sulfone. This simple and robust process employs low-intensity ultrasound, air-stable CuII/L catalysts, and carbonate or bicarbonate salts (washing soda or baking soda) to prepare well-defined polyacrylates.
AbstractList Atom transfer radical polymerization (ATRP) has been previously mediated by ultrasound using a low concentration of copper complex in water (sono-ATRP) or by addition of piezoelectric materials in organic solvents (mechano-ATRP). However, these procedures proceeded slowly and yielded polymers contaminated by new chains initiated by hydroxyl radicals or by residual piezoelectrics. Unexpectedly, in the presence of sodium carbonate, rapid sono-ATRP of methyl acrylate in DMSO was achieved (80% conversion in <2 h) with excellent control of molecular weights and low dispersities (Mw/Mn < 1.2). The in situ formed CuII/L-CO3 complex in the the presence of ultrasound generated CuI/L species as activators for ATRP and carbonate radical anions. The latter were scavenged by DMSO that was oxidized to dimethyl sulfone. This simple and robust process employs low-intensity ultrasound, air-stable CuII/L catalysts, and carbonate or bicarbonate salts (washing soda or baking soda) to prepare well-defined polyacrylates.Atom transfer radical polymerization (ATRP) has been previously mediated by ultrasound using a low concentration of copper complex in water (sono-ATRP) or by addition of piezoelectric materials in organic solvents (mechano-ATRP). However, these procedures proceeded slowly and yielded polymers contaminated by new chains initiated by hydroxyl radicals or by residual piezoelectrics. Unexpectedly, in the presence of sodium carbonate, rapid sono-ATRP of methyl acrylate in DMSO was achieved (80% conversion in <2 h) with excellent control of molecular weights and low dispersities (Mw/Mn < 1.2). The in situ formed CuII/L-CO3 complex in the the presence of ultrasound generated CuI/L species as activators for ATRP and carbonate radical anions. The latter were scavenged by DMSO that was oxidized to dimethyl sulfone. This simple and robust process employs low-intensity ultrasound, air-stable CuII/L catalysts, and carbonate or bicarbonate salts (washing soda or baking soda) to prepare well-defined polyacrylates.
Atom transfer radical polymerization (ATRP) has been previously mediated by ultrasound using a low concentration of copper complex in water (sono-ATRP) or by addition of piezoelectric materials in organic solvents (mechano-ATRP). However, these procedures proceeded slowly and yielded polymers contaminated by new chains initiated by hydroxyl radicals or by residual piezoelectrics. Unexpectedly, in the presence of sodium carbonate, rapid sono-ATRP of methyl acrylate in DMSO was achieved (80% conversion in <2 h) with excellent control of molecular weights and low dispersities (M w/M n < 1.2). The in situ formed CuII/L-CO3 complex in the the presence of ultrasound generated CuI/L species as activators for ATRP and carbonate radical anions. The latter were scavenged by DMSO that was oxidized to dimethyl sulfone. This simple and robust process employs low-intensity ultrasound, air-stable CuII/L catalysts, and carbonate or bicarbonate salts (washing soda or baking soda) to prepare well-defined polyacrylates.
Atom transfer radical polymerization (ATRP) has been previously mediated by ultrasound using a low concentration of copper complex in water (sono-ATRP) or by addition of piezoelectric materials in organic solvents (mechano-ATRP). However, these procedures proceeded slowly and yielded polymers contaminated by new chains initiated by hydroxyl radicals or by residual piezoelectrics. Unexpectedly, in the presence of sodium carbonate, rapid sono-ATRP of methyl acrylate in DMSO was achieved (80% conversion in <2 h) with excellent control of molecular weights and low dispersities ( / < 1.2). The formed Cu /L-CO complex in the the presence of ultrasound generated Cu /L species as activators for ATRP and carbonate radical anions. The latter were scavenged by DMSO that was oxidized to dimethyl sulfone. This simple and robust process employs low-intensity ultrasound, air-stable Cu /L catalysts, and carbonate or bicarbonate salts (washing soda or baking soda) to prepare well-defined polyacrylates.
Author Matyjaszewski, Krzysztof
Lorandi, Francesca
Xia, Hesheng
Wang, Zhanhua
Wang, Zhenhua
Fantin, Marco
Wang, Zongyu
Yan, Jiajun
AuthorAffiliation Department of Chemistry
The State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute
AuthorAffiliation_xml – name: The State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute
– name: Department of Chemistry
Author_xml – sequence: 1
  givenname: Zhenhua
  orcidid: 0000-0002-9028-6799
  surname: Wang
  fullname: Wang, Zhenhua
  organization: Department of Chemistry
– sequence: 2
  givenname: Francesca
  surname: Lorandi
  fullname: Lorandi, Francesca
  organization: Department of Chemistry
– sequence: 3
  givenname: Marco
  surname: Fantin
  fullname: Fantin, Marco
  organization: Department of Chemistry
– sequence: 4
  givenname: Zongyu
  surname: Wang
  fullname: Wang, Zongyu
  organization: Department of Chemistry
– sequence: 5
  givenname: Jiajun
  orcidid: 0000-0003-3286-3268
  surname: Yan
  fullname: Yan, Jiajun
  organization: Department of Chemistry
– sequence: 6
  givenname: Zhanhua
  orcidid: 0000-0003-0493-1905
  surname: Wang
  fullname: Wang, Zhanhua
  organization: The State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute
– sequence: 7
  givenname: Hesheng
  surname: Xia
  fullname: Xia, Hesheng
  email: xiahs@scu.edu.cn
  organization: The State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute
– sequence: 8
  givenname: Krzysztof
  orcidid: 0000-0003-1960-3402
  surname: Matyjaszewski
  fullname: Matyjaszewski, Krzysztof
  email: km3b@andrew.cmu.edu
  organization: Department of Chemistry
BackLink https://www.ncbi.nlm.nih.gov/pubmed/35619423$$D View this record in MEDLINE/PubMed
BookMark eNqFkE1rVDEUQINUbK39ByJZunk1N-9z3JWhfsBApZ1VN4-bvBtMyUvGJG8x_nrTzijFha5yIedcLuc1O_HBE2NvQVyCkPABdZpRx-Ao58uVEkLI1Qt2JqGDCrq2Pnk2n7KLlB4KItoOhlXzip3WZVo1sj5j91c5zHwb0SdDkd_iZDU6_i24_UzR_sRsg-fXHpWjias9vws-6O80P2JuzzeorCO-XiqNUQWPmfjdjrSl9Ia9NOgSXRzfc7b9dL1df6k2N5-_rq82FTbQ5MqALkf2QEZ3gxqacpvoWoEKtBw63dSNVMJoMm2tp1biAFNvTG9Ea2Q7QX3O3h_W7mL4sVDK42yTJufQU1jSKLseZD8AdAV9d0QXNdM07qKdMe7H3zkK0ByAkjalSOYPAmJ8DD8-Dz8ewxft41-atvmpXI5o3f9kcZDL7_gQluhLrH8rvwA9hZ6G
CitedBy_id crossref_primary_10_1021_jacs_2c05364
crossref_primary_10_1360_TB_2024_0311
crossref_primary_10_1002_aic_17151
crossref_primary_10_1002_marc_202100211
crossref_primary_10_1002_marc_202400235
crossref_primary_10_1016_j_eurpolymj_2022_111735
crossref_primary_10_1002_macp_201900496
crossref_primary_10_1002_macp_202000092
crossref_primary_10_1002_pat_4921
crossref_primary_10_1021_acscatal_0c03802
crossref_primary_10_1002_marc_202300029
crossref_primary_10_1039_C9PY01742A
crossref_primary_10_1016_j_ultsonch_2020_105163
crossref_primary_10_1021_acs_macromol_3c00250
crossref_primary_10_1016_j_eurpolymj_2022_111143
crossref_primary_10_1016_j_eurpolymj_2023_112374
crossref_primary_10_3390_ma12213600
crossref_primary_10_1002_ange_202309440
crossref_primary_10_1016_j_polymer_2023_125885
crossref_primary_10_1039_D2GC03558H
crossref_primary_10_1016_j_eurpolymj_2024_112839
crossref_primary_10_1039_D0PY01672A
crossref_primary_10_1016_j_pmatsci_2023_101113
crossref_primary_10_1007_s13233_020_8091_3
crossref_primary_10_1021_acsmacrolett_9b00576
crossref_primary_10_1021_acs_macromol_2c01114
crossref_primary_10_1021_acs_macromol_0c02702
crossref_primary_10_1039_D0SC03179H
crossref_primary_10_1021_acs_macromol_0c00888
crossref_primary_10_1002_anie_202005021
crossref_primary_10_1002_ijch_201900079
crossref_primary_10_3390_ma13071717
crossref_primary_10_1016_j_ultsonch_2020_105384
crossref_primary_10_1038_s41467_024_50562_z
crossref_primary_10_1016_j_memsci_2025_123885
crossref_primary_10_1016_j_ultsonch_2020_105305
crossref_primary_10_1016_j_progpolymsci_2019_101180
crossref_primary_10_1021_acs_orglett_4c00613
crossref_primary_10_1021_acs_chemrev_9b00744
crossref_primary_10_1002_app_49275
crossref_primary_10_1002_ange_202005021
crossref_primary_10_1016_j_cis_2022_102683
crossref_primary_10_1021_acsomega_0c04356
crossref_primary_10_1039_D2PY00682K
crossref_primary_10_1016_j_eurpolymj_2022_111201
crossref_primary_10_1016_j_cej_2023_142642
crossref_primary_10_1039_D4LC00591K
crossref_primary_10_1126_science_aay8224
crossref_primary_10_1016_j_ultsonch_2021_105878
crossref_primary_10_1002_aic_16746
crossref_primary_10_1002_macp_202200347
crossref_primary_10_1002_anie_202309440
crossref_primary_10_1016_j_polymer_2022_124949
crossref_primary_10_1021_acs_jpclett_2c01106
crossref_primary_10_1002_cplu_202400287
crossref_primary_10_1002_celc_202000131
Cites_doi 10.1002/anie.201206476
10.1021/jacs.5b13455
10.1039/C5CS00096C
10.1002/anie.201505678
10.1021/acs.macromol.8b01845
10.1021/cm0109591
10.1039/C8CS00259B
10.1002/anie.201605909
10.1021/mz4001817
10.1016/S0045-6535(00)00042-4
10.1021/acsmacrolett.8b00497
10.1021/acs.macromol.7b01597
10.1021/ja501745g
10.1021/cr940534g
10.1002/anie.201706771
10.1002/anie.201805473
10.1021/ma3001719
10.1126/science.1202357
10.1021/ja510389m
10.1021/ja2036089
10.1021/acsmacrolett.7b00152
10.1021/jacs.5b05903
10.1039/C6CC01413E
10.1002/adma.201706441
10.1021/jacs.7b06661
10.1021/jacs.5b11599
10.1038/nchem.167
10.1016/j.coelec.2017.11.004
10.1021/ma00109a056
10.1039/C8PY00456K
10.1126/science.1193928
10.1073/pnas.0602675103
10.1021/jacs.7b01694
10.1021/ja505883u
10.1021/ja049494g
10.1021/ja00125a035
10.1021/acs.chemrev.5b00426
10.1021/jacs.8b00173
10.1021/ja200883z
10.1038/nchem.2633
10.1002/adma.200904093
10.1002/anie.201804111
10.1002/anie.201802964
10.1021/ja508371q
10.1021/jacs.6b10345
10.1021/ja0676657
10.1021/acsmacrolett.8b00027
ContentType Journal Article
DBID AAYXX
CITATION
NPM
7X8
DOI 10.1021/acsmacrolett.9b00029
DatabaseName CrossRef
PubMed
MEDLINE - Academic
DatabaseTitle CrossRef
PubMed
MEDLINE - Academic
DatabaseTitleList MEDLINE - Academic

PubMed
Database_xml – sequence: 1
  dbid: NPM
  name: PubMed
  url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed
  sourceTypes: Index Database
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 2161-1653
EndPage 165
ExternalDocumentID 35619423
10_1021_acsmacrolett_9b00029
i86127243
Genre Journal Article
GroupedDBID 55A
7~N
AABXI
ABMVS
ABUCX
ACGFS
ACS
AEESW
AENEX
AFEFF
ALMA_UNASSIGNED_HOLDINGS
AQSVZ
ED
ED~
GNL
IH9
JG
JG~
ROL
UI2
VF5
VG9
W1F
AAYXX
ABBLG
ABJNI
ABLBI
ABQRX
ADHLV
BAANH
CITATION
CUPRZ
EBS
GGK
NPM
7X8
ID FETCH-LOGICAL-a414t-f1c65371efc68b843560650ab1c286c4342b0fcef53cd52a81d7ff7f05f25d13
IEDL.DBID ACS
ISSN 2161-1653
IngestDate Fri Jul 11 11:24:22 EDT 2025
Mon Jul 21 05:53:06 EDT 2025
Tue Jul 01 01:35:11 EDT 2025
Thu Apr 24 23:11:26 EDT 2025
Thu Aug 27 13:44:18 EDT 2020
IsPeerReviewed false
IsScholarly true
Issue 2
Language English
License https://doi.org/10.15223/policy-029
https://doi.org/10.15223/policy-037
https://doi.org/10.15223/policy-045
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-a414t-f1c65371efc68b843560650ab1c286c4342b0fcef53cd52a81d7ff7f05f25d13
Notes ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ORCID 0000-0002-9028-6799
0000-0003-0493-1905
0000-0003-1960-3402
0000-0003-3286-3268
PMID 35619423
PQID 2671278116
PQPubID 23479
PageCount 5
ParticipantIDs proquest_miscellaneous_2671278116
pubmed_primary_35619423
crossref_primary_10_1021_acsmacrolett_9b00029
crossref_citationtrail_10_1021_acsmacrolett_9b00029
acs_journals_10_1021_acsmacrolett_9b00029
ProviderPackageCode JG~
55A
AABXI
GNL
VF5
7~N
VG9
W1F
ACS
AEESW
AFEFF
ABMVS
ABUCX
IH9
AQSVZ
ED~
UI2
CITATION
AAYXX
PublicationCentury 2000
PublicationDate 2019-02-19
PublicationDateYYYYMMDD 2019-02-19
PublicationDate_xml – month: 02
  year: 2019
  text: 2019-02-19
  day: 19
PublicationDecade 2010
PublicationPlace United States
PublicationPlace_xml – name: United States
PublicationTitle ACS macro letters
PublicationTitleAlternate ACS Macro Lett
PublicationYear 2019
Publisher American Chemical Society
Publisher_xml – name: American Chemical Society
References ref9/cit9
ref15/cit15a
ref15/cit15b
ref13/cit13a
ref16/cit16
ref8/cit8a
ref13/cit13b
ref8/cit8c
ref8/cit8b
ref8/cit8e
ref12/cit12c
ref8/cit8d
ref12/cit12b
ref12/cit12a
ref8/cit8f
ref2/cit2
ref5/cit5b
ref10/cit10
ref5/cit5a
ref6/cit6d
ref4/cit4a
ref4/cit4b
ref4/cit4c
ref14/cit14a
ref11/cit11f
ref14/cit14b
ref3/cit3b
ref11/cit11c
ref3/cit3c
ref11/cit11b
ref11/cit11e
ref3/cit3a
ref11/cit11d
ref11/cit11a
ref4/cit4d
ref4/cit4e
ref6/cit6a
ref1/cit1
ref4/cit4f
ref6/cit6b
ref4/cit4g
ref6/cit6c
ref4/cit4h
ref4/cit4i
ref4/cit4j
ref4/cit4k
ref7/cit7
References_xml – ident: ref3/cit3a
  doi: 10.1002/anie.201206476
– ident: ref6/cit6b
  doi: 10.1021/jacs.5b13455
– ident: ref2/cit2
  doi: 10.1039/C5CS00096C
– ident: ref10/cit10
  doi: 10.1002/anie.201505678
– ident: ref13/cit13b
  doi: 10.1021/acs.macromol.8b01845
– ident: ref8/cit8a
  doi: 10.1021/cm0109591
– ident: ref3/cit3c
  doi: 10.1039/C8CS00259B
– ident: ref8/cit8b
  doi: 10.1002/anie.201605909
– ident: ref8/cit8c
  doi: 10.1021/mz4001817
– ident: ref16/cit16
  doi: 10.1016/S0045-6535(00)00042-4
– ident: ref4/cit4i
  doi: 10.1021/acsmacrolett.8b00497
– ident: ref12/cit12c
  doi: 10.1021/acs.macromol.7b01597
– ident: ref4/cit4g
  doi: 10.1021/ja501745g
– ident: ref11/cit11d
  doi: 10.1021/cr940534g
– ident: ref13/cit13a
  doi: 10.1002/anie.201706771
– ident: ref4/cit4d
  doi: 10.1002/anie.201805473
– ident: ref11/cit11c
  doi: 10.1021/ma3001719
– ident: ref4/cit4e
  doi: 10.1126/science.1202357
– ident: ref5/cit5a
  doi: 10.1021/ja510389m
– ident: ref4/cit4j
  doi: 10.1021/ja2036089
– ident: ref12/cit12b
  doi: 10.1021/acsmacrolett.7b00152
– ident: ref4/cit4c
  doi: 10.1021/jacs.5b05903
– ident: ref15/cit15b
  doi: 10.1039/C6CC01413E
– ident: ref11/cit11e
  doi: 10.1002/adma.201706441
– ident: ref4/cit4a
  doi: 10.1021/jacs.7b06661
– ident: ref6/cit6a
  doi: 10.1021/jacs.5b11599
– ident: ref9/cit9
  doi: 10.1038/nchem.167
– ident: ref11/cit11f
  doi: 10.1016/j.coelec.2017.11.004
– ident: ref11/cit11b
  doi: 10.1021/ma00109a056
– ident: ref14/cit14b
  doi: 10.1039/C8PY00456K
– ident: ref1/cit1
  doi: 10.1126/science.1193928
– ident: ref6/cit6d
  doi: 10.1073/pnas.0602675103
– ident: ref5/cit5b
  doi: 10.1021/jacs.7b01694
– ident: ref4/cit4k
  doi: 10.1021/ja505883u
– ident: ref8/cit8d
  doi: 10.1021/ja049494g
– ident: ref11/cit11a
  doi: 10.1021/ja00125a035
– ident: ref3/cit3b
  doi: 10.1021/acs.chemrev.5b00426
– ident: ref4/cit4b
  doi: 10.1021/jacs.8b00173
– ident: ref8/cit8f
  doi: 10.1021/ja200883z
– ident: ref12/cit12a
  doi: 10.1038/nchem.2633
– ident: ref7/cit7
  doi: 10.1002/adma.200904093
– ident: ref4/cit4h
  doi: 10.1002/anie.201804111
– ident: ref6/cit6c
  doi: 10.1002/anie.201802964
– ident: ref15/cit15a
  doi: 10.1021/ja508371q
– ident: ref4/cit4f
  doi: 10.1021/jacs.6b10345
– ident: ref8/cit8e
  doi: 10.1021/ja0676657
– ident: ref14/cit14a
  doi: 10.1021/acsmacrolett.8b00027
SSID ssj0000561894
Score 2.4218163
Snippet Atom transfer radical polymerization (ATRP) has been previously mediated by ultrasound using a low concentration of copper complex in water (sono-ATRP) or by...
SourceID proquest
pubmed
crossref
acs
SourceType Aggregation Database
Index Database
Enrichment Source
Publisher
StartPage 161
Title Atom Transfer Radical Polymerization Enabled by Sonochemically Labile Cu-carbonate Species
URI http://dx.doi.org/10.1021/acsmacrolett.9b00029
https://www.ncbi.nlm.nih.gov/pubmed/35619423
https://www.proquest.com/docview/2671278116
Volume 8
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwlV1LTxsxELYoHOACLY8SaCsj9cLBIfb6sXuMoqAI0YJKKkVcVrbXvjTsouzmEH49tnc3FKoo9L625JnZmc_zeWYA-C6wSaxmzvtJKhB1vhF5FI5YZBWmFisa8pA_fvLRb3o1YZOXi-JbBp_gC6nLB6n9W7uq6iaBG0s-gC3CY-EvW_3B3TKn4tFwHGYfEgdkEOYsaqvlVmzkY5IuX8ekFUAzBJzLPXDTlu3U70z-dOeV6uqnf7s4vvMsH8Fugz1hvzaWT2DD5Ptge9COfDsA9_2qeIAhfFkzg79kIHHgbTFdeGKnrtiEw1BulUG1gHdF7iduhZYD0wW89u16DRzMkZYz5fPyBoYB96Y8BOPL4XgwQs3wBSQpphWyWDvxOVVazWMVO1TFPZqTCmsSc00jSlTPamNZpDNGpMO9wlphe8wSluHoCGzmRW6OAbTcd7U3zo86vQuVxUwqT99ZIkSmelEHnDu5pM2_U6aBFic4_VtYaSOsDohaTaW6aWLuZ2lM16xCy1WPdROPNd-ftUaQOg14CkXmppiXKeECE1-cyzvgc20dyx2dhHDi0OnJf5znFOw4BJb4Z-A4-QI2q9ncfHUop1Lfgmk_Awsc-d0
linkProvider American Chemical Society
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwzV1LbxMxEB6VcigXypuUl5HgwGHT2Gvv48AhCq1SmlaIBKniYtle-0K6W2U3QuH38Ff4X4yd3fCQqopDJa6r9XPGM589L4BXKbW5MwKln-JpxFE2Rh6FRyJ2mnJHNQ_vkCenyfgTf38mzrbgexcLg5Oosac6GPF_ZReg-_jtXBnvctc0_TyYyPLWl_LYrr7iTa1-e_QOyfqascOD2WgctcUEIsUpbyJHTSJinJozSaYzRAmJRydKU8OyxPCYMz1wxjoRm0IwhTgudS51A-GYKGiM3d6Amwh_mL_iDUfTzUuOx-BZqLjIED5FFIfpYvQumbfXhKb-UxNeAm-DmjvchR-bDQreLV_6y0b3zbe_ckf-7zt4B263OJsM1wfjLmzZ8h7sjLrydvfh87CpzklQ1c4uyEcVDFbkQzVfeSPWOjqVHITQsoLoFZlWpa8uFtIrzFdk4lMTWzJaRkYttLdBWDK9sCgq6wcwu46VPYTtsirtYyAu8Rn8LeoM5PFUF5lQ2psqHUvTQg_iHrxBMshWTtQyuAAwKn-njWxp04O44w9p2oTtvm7I_IpW0abVxTphyRX_v-xYTyIFvLlIlbZa1pIlKWU-EDnpwaM1T256xB2iOSLxvX9YzwvYGc9OJnJydHr8BG4h8sy9-zvNn8J2s1jaZ4juGv08HC4C8ppZ8Seb_ltu
linkToPdf http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMw1V1Lb9QwEB6VIgEXypulPIwEBw7Zrh07jwOH1barlpaqYotUcbFsx76wTVabrNDyi_gr_Vcde5MVIFUVhx64Rolje8aez_7mAfAupTZ3RuDup3gacdwbI4_CIxE7Tbmjmod7yM_Hyf5X_ulMnG3Ary4WBjtRY0t1IPH9qp4Vrs0wQHfw-bky3u2uafp5oMny1p_y0C5_4Gmt_niwi6J9z9h473S0H7UFBSLFKW8iR00iYuyeM0mmM0QKiUcoSlPDssTwmDM9cMY6EZtCMIVYLnUudQPhmChojM3egtueKPTHvOFosr7N8Tg8C1UXGUKoiOJvuji9K_rtraGp_7SGV0DcYOrGW3CxnqTg4fK9v2h03_z8K3_k_zCLD-B-i7fJcLVAHsKGLR_B3VFX5u4xfBs21TkJJtvZOfmiAnFFTqrp0pNZqyhVshdCzAqil2RSlb7KWEizMF2SI5-i2JLRIjJqrj0XYclkZnHLrJ_A6U2M7ClsllVpnwNxic_kb9F2oK6nusiE0p6ydCxNCz2Ie_ABxSDb_aKWwRWAUfm7bGQrmx7EnY5I0yZu9_VDptd8Fa2_mq0Sl1zz_ttO_SRKwNNGqrTVopYsSSnzAclJD56t9HLdIs4QzRGRv_iH8byBOye7Y3l0cHy4DfcQgObeC57mL2GzmS_sKwR5jX4d1hcBecOaeAn3s13x
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Atom+Transfer+Radical+Polymerization+Enabled+by+Sonochemically+Labile+Cu-carbonate+Species&rft.jtitle=ACS+macro+letters&rft.au=Wang%2C+Zhenhua&rft.au=Lorandi%2C+Francesca&rft.au=Fantin%2C+Marco&rft.au=Wang%2C+Zongyu&rft.date=2019-02-19&rft.pub=American+Chemical+Society&rft.issn=2161-1653&rft.eissn=2161-1653&rft.volume=8&rft.issue=2&rft.spage=161&rft.epage=165&rft_id=info:doi/10.1021%2Facsmacrolett.9b00029&rft.externalDocID=i86127243
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=2161-1653&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=2161-1653&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=2161-1653&client=summon