Pd(II)-Catalyzed Phosphorylation of Aryl C–H Bonds

A Pd(II)-catalyzed C–H phosphorylation reaction has been developed using heterocycle-directed ortho-palladation. Both H-phosphonates and diaryl phosphine oxides are suitable coupling partners for this reaction.

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 135; no. 25; pp. 9322 - 9325
Main Authors Feng, Chen-Guo, Ye, Mengchun, Xiao, Kai-Jiong, Li, Suhua, Yu, Jin-Quan
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 26.06.2013
Amer Chemical Soc
Subjects
Catalysis
chemical bonding
Chemistry
Chemistry, Multidisciplinary
Molecular Structure
Organometallic Compounds - chemistry
Organophosphonates - chemistry
oxides
Oxides - chemistry
Palladium - chemistry
phosphine
Phosphines - chemistry
Phosphorylation
Physical Sciences
Pyridines - chemical synthesis
Pyridines - chemistry
Science & Technology
ACIDS
PHOSPHONATION
CONSTRUCTION
DIPHENYLPHOSPHINE
ORTHO-ARYLATION
LIGAND
HYDROGEN PHOSPHATES
PHOSPHINE OXIDES
ALKENYLATION
PALLADIUM-CATALYZED ALKYLATION
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Abstract A Pd(II)-catalyzed C–H phosphorylation reaction has been developed using heterocycle-directed ortho-palladation. Both H-phosphonates and diaryl phosphine oxides are suitable coupling partners for this reaction.
AbstractList A Pd(II)-catalyzed C-H phosphorylation reaction has been developed using heterocycle-directed ortho-palladation. Both H-phosphonates and diaryl phosphine oxides are suitable coupling partners for this reaction.A Pd(II)-catalyzed C-H phosphorylation reaction has been developed using heterocycle-directed ortho-palladation. Both H-phosphonates and diaryl phosphine oxides are suitable coupling partners for this reaction.
A Pd(II)-catalyzed C–H phosphorylation reaction has been developed using heterocycle-directed ortho-palladation. Both H-phosphonates and diaryl phosphine oxides are suitable coupling partners for this reaction.
Author Li, Suhua
Xiao, Kai-Jiong
Ye, Mengchun
Feng, Chen-Guo
Yu, Jin-Quan
AuthorAffiliation The Scripps Research Institute
AuthorAffiliation_xml – name: The Scripps Research Institute
Author_xml – sequence: 1
  givenname: Chen-Guo
  surname: Feng
  fullname: Feng, Chen-Guo
– sequence: 2
  givenname: Mengchun
  surname: Ye
  fullname: Ye, Mengchun
– sequence: 3
  givenname: Kai-Jiong
  surname: Xiao
  fullname: Xiao, Kai-Jiong
– sequence: 4
  givenname: Suhua
  surname: Li
  fullname: Li, Suhua
– sequence: 5
  givenname: Jin-Quan
  surname: Yu
  fullname: Yu, Jin-Quan
  email: yu200@scripps.edu
BackLink https://www.ncbi.nlm.nih.gov/pubmed/23755825$$D View this record in MEDLINE/PubMed
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IsPeerReviewed true
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Issue 25
Keywords ACIDS
PHOSPHONATION
CONSTRUCTION
DIPHENYLPHOSPHINE
ORTHO-ARYLATION
LIGAND
HYDROGEN PHOSPHATES
PHOSPHINE OXIDES
ALKENYLATION
PALLADIUM-CATALYZED ALKYLATION
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Snippet A Pd(II)-catalyzed C–H phosphorylation reaction has been developed using heterocycle-directed ortho-palladation. Both H-phosphonates and diaryl phosphine...
A Pd(II)-catalyzed C-H phosphorylation reaction has been developed using heterocycle-directed ortho-palladation. Both H-phosphonates and diaryl phosphine...
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SubjectTerms Catalysis
chemical bonding
Chemistry
Chemistry, Multidisciplinary
Molecular Structure
Organometallic Compounds - chemistry
Organophosphonates - chemistry
oxides
Oxides - chemistry
Palladium - chemistry
phosphine
Phosphines - chemistry
Phosphorylation
Physical Sciences
Pyridines - chemical synthesis
Pyridines - chemistry
Science & Technology
Title Pd(II)-Catalyzed Phosphorylation of Aryl C–H Bonds
URI http://dx.doi.org/10.1021/ja404526x
http://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestApp=WOS&DestLinkType=FullRecord&UT=000321236600023
https://www.ncbi.nlm.nih.gov/pubmed/23755825
https://www.proquest.com/docview/1372077560
https://www.proquest.com/docview/2986230329
Volume 135
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