Pd(II)-Catalyzed Phosphorylation of Aryl C–H Bonds

A Pd(II)-catalyzed C–H phosphorylation reaction has been developed using heterocycle-directed ortho-palladation. Both H-phosphonates and diaryl phosphine oxides are suitable coupling partners for this reaction.

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 135; no. 25; pp. 9322 - 9325
Main Authors Feng, Chen-Guo, Ye, Mengchun, Xiao, Kai-Jiong, Li, Suhua, Yu, Jin-Quan
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 26.06.2013
Amer Chemical Soc
Subjects
Catalysis
chemical bonding
Chemistry
Chemistry, Multidisciplinary
Molecular Structure
Organometallic Compounds - chemistry
Organophosphonates - chemistry
oxides
Oxides - chemistry
Palladium - chemistry
phosphine
Phosphines - chemistry
Phosphorylation
Physical Sciences
Pyridines - chemical synthesis
Pyridines - chemistry
Science & Technology
ACIDS
PHOSPHONATION
CONSTRUCTION
DIPHENYLPHOSPHINE
ORTHO-ARYLATION
LIGAND
HYDROGEN PHOSPHATES
PHOSPHINE OXIDES
ALKENYLATION
PALLADIUM-CATALYZED ALKYLATION
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Summary:A Pd(II)-catalyzed C–H phosphorylation reaction has been developed using heterocycle-directed ortho-palladation. Both H-phosphonates and diaryl phosphine oxides are suitable coupling partners for this reaction.
Bibliography:National Science Foundation
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0002-7863
1520-5126
1520-5126
DOI:10.1021/ja404526x