Direct Radical Acetoxyphosphorylation of Styrenes Mediated by Manganese(III)

• Published in: Journal of organic chemistry Vol. 80; no. 2; pp. 1214 - 1220
• Main Authors: Zhou, Shao-Fang, Li, Da-Peng, Liu, Kui, Zou, Jian-Ping, Asekun, Olayinka Taiwo
• Format: Journal Article
• Language: English
• Published: WASHINGTON American Chemical Society 16.01.2015; Amer Chemical Soc
• Subjects: alkenes; Alkenes - chemistry; chemical reactions; chemical structure; Chemistry; Chemistry, Organic; manganese; Manganese - chemistry; Molecular Structure; organic chemistry; Organophosphorus Compounds - chemistry; Phosphites - chemistry; Phosphorylation; Physical Sciences; Science & Technology; Styrenes - chemistry; HYDROPHOSPHINATION; ALKENES; 2-ISOCYANOBIPHENYLS; PHOSPHONATES; MECHANISM; PHOSPHONYLATION; PHOSPHINES; OXIDATIVE CYCLIZATION; ALKYNES; COUMARINS

Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)3 with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of difunctionalization of alkenes was achieved.