Direct Radical Acetoxyphosphorylation of Styrenes Mediated by Manganese(III)

Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)3 with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of difunctionalization of alkenes was achieved.

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Bibliographic Details
Published inJournal of organic chemistry Vol. 80; no. 2; pp. 1214 - 1220
Main Authors Zhou, Shao-Fang, Li, Da-Peng, Liu, Kui, Zou, Jian-Ping, Asekun, Olayinka Taiwo
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 16.01.2015
Amer Chemical Soc
Subjects
alkenes
Alkenes - chemistry
chemical reactions
chemical structure
Chemistry
Chemistry, Organic
manganese
Manganese - chemistry
Molecular Structure
organic chemistry
Organophosphorus Compounds - chemistry
Phosphites - chemistry
Phosphorylation
Physical Sciences
Science & Technology
Styrenes - chemistry
HYDROPHOSPHINATION
ALKENES
2-ISOCYANOBIPHENYLS
PHOSPHONATES
MECHANISM
PHOSPHONYLATION
PHOSPHINES
OXIDATIVE CYCLIZATION
ALKYNES
COUMARINS
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Summary:Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)3 with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of difunctionalization of alkenes was achieved.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0022-3263
1520-6904
1520-6904
DOI:10.1021/jo5023298