Direct Radical Acetoxyphosphorylation of Styrenes Mediated by Manganese(III)

Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)3 with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of difunctionalization of alkenes was achieved.

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Bibliographic Details
Published inJournal of organic chemistry Vol. 80; no. 2; pp. 1214 - 1220
Main Authors Zhou, Shao-Fang, Li, Da-Peng, Liu, Kui, Zou, Jian-Ping, Asekun, Olayinka Taiwo
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 16.01.2015
Amer Chemical Soc
Subjects
alkenes
Alkenes - chemistry
chemical reactions
chemical structure
Chemistry
Chemistry, Organic
manganese
Manganese - chemistry
Molecular Structure
organic chemistry
Organophosphorus Compounds - chemistry
Phosphites - chemistry
Phosphorylation
Physical Sciences
Science & Technology
Styrenes - chemistry
HYDROPHOSPHINATION
ALKENES
2-ISOCYANOBIPHENYLS
PHOSPHONATES
MECHANISM
PHOSPHONYLATION
PHOSPHINES
OXIDATIVE CYCLIZATION
ALKYNES
COUMARINS
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Abstract Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)3 with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of difunctionalization of alkenes was achieved.
AbstractList Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)₃ with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of difunctionalization of alkenes was achieved.
Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)3 with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of difunctionalization of alkenes was achieved.
Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)3 with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of difunctionalization of alkenes was achieved.Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)3 with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of difunctionalization of alkenes was achieved.
Author Zhou, Shao-Fang
Liu, Kui
Zou, Jian-Ping
Li, Da-Peng
Asekun, Olayinka Taiwo
AuthorAffiliation Department of Chemistry
Chinese Academy of Sciences
Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering
Soochow University
University of Lagos
AuthorAffiliation_xml – name: Soochow University
– name: Department of Chemistry
– name: University of Lagos
– name: Chinese Academy of Sciences
– name: Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering
– name: Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry
Author_xml – sequence: 1
  givenname: Shao-Fang
  surname: Zhou
  fullname: Zhou, Shao-Fang
– sequence: 2
  givenname: Da-Peng
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  surname: Liu
  fullname: Liu, Kui
– sequence: 4
  givenname: Jian-Ping
  surname: Zou
  fullname: Zou, Jian-Ping
  email: jpzou@suda.edu.cn
– sequence: 5
  givenname: Olayinka Taiwo
  surname: Asekun
  fullname: Asekun, Olayinka Taiwo
BackLink https://www.ncbi.nlm.nih.gov/pubmed/25490256$$D View this record in MEDLINE/PubMed
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Issue 2
Keywords HYDROPHOSPHINATION
ALKENES
2-ISOCYANOBIPHENYLS
PHOSPHONATES
MECHANISM
PHOSPHONYLATION
PHOSPHINES
OXIDATIVE CYCLIZATION
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Snippet Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)3 with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of...
Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)(3) with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of...
Direct radical acetoxyphosphorylation of styrenes mediated by Mn(OAc)₃ with diphenylphosphine oxide and dialkyl phosphites was described, and a new type of...
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SubjectTerms alkenes
Alkenes - chemistry
chemical reactions
chemical structure
Chemistry
Chemistry, Organic
manganese
Manganese - chemistry
Molecular Structure
organic chemistry
Organophosphorus Compounds - chemistry
Phosphites - chemistry
Phosphorylation
Physical Sciences
Science & Technology
Styrenes - chemistry
Title Direct Radical Acetoxyphosphorylation of Styrenes Mediated by Manganese(III)
URI http://dx.doi.org/10.1021/jo5023298
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https://www.ncbi.nlm.nih.gov/pubmed/25490256
https://www.proquest.com/docview/1677888281
https://www.proquest.com/docview/2000553005
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