A Microporous Hydrogen-Bonded Organic Framework: Exceptional Stability and Highly Selective Adsorption of Gas and Liquid

• Published in: Journal of the American Chemical Society Vol. 135; no. 32; pp. 11684 - 11687
• Main Authors: Luo, Xu-Zhong, Jia, Xin-Jian, Deng, Ji-Hua, Zhong, Jin-Lian, Liu, Hui-Jin, Wang, Ke-Jun, Zhong, Di-Chang
• Format: Journal Article
• Language: English
• Published: WASHINGTON American Chemical Society 14.08.2013; Amer Chemical Soc
• Subjects: Adsorption; ambient temperature; Benzamides - chemistry; Benzene - isolation & purification; carbon dioxide; Carbon Dioxide - isolation & purification; Chemistry; Chemistry, Multidisciplinary; Gases - isolation & purification; Hydrogen Bonding; Models, Molecular; Physical Sciences; Porosity; porous media; Science & Technology; solvents; THERMAL-STABILITY; POROSITY; STORAGE; CARBON-DIOXIDE CAPTURE; HYDROCARBONS; NETWORKS; CRYSTAL; SEPARATION; QUADRUPOLE-MOMENTS; CO2 CAPTURE

An extremely stable hydrogen-bonded organic framework, HOF-8, was fabricated. HOF-8 is not only thermally stable but also stable in water and common organic solvents. More interestingly, desolvated HOF-8 exhibits high CO2 adsorption as well as highly selective CO2 and C6H6 adsorption at ambient temp...