A Microporous Hydrogen-Bonded Organic Framework: Exceptional Stability and Highly Selective Adsorption of Gas and Liquid

An extremely stable hydrogen-bonded organic framework, HOF-8, was fabricated. HOF-8 is not only thermally stable but also stable in water and common organic solvents. More interestingly, desolvated HOF-8 exhibits high CO2 adsorption as well as highly selective CO2 and C6H6 adsorption at ambient temp...

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Published inJournal of the American Chemical Society Vol. 135; no. 32; pp. 11684 - 11687
Main Authors Luo, Xu-Zhong, Jia, Xin-Jian, Deng, Ji-Hua, Zhong, Jin-Lian, Liu, Hui-Jin, Wang, Ke-Jun, Zhong, Di-Chang
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 14.08.2013
Amer Chemical Soc
Subjects
Adsorption
ambient temperature
Benzamides - chemistry
Benzene - isolation & purification
carbon dioxide
Carbon Dioxide - isolation & purification
Chemistry
Chemistry, Multidisciplinary
Gases - isolation & purification
Hydrogen Bonding
Models, Molecular
Physical Sciences
Porosity
porous media
Science & Technology
solvents
THERMAL-STABILITY
POROSITY
STORAGE
CARBON-DIOXIDE CAPTURE
HYDROCARBONS
NETWORKS
CRYSTAL
SEPARATION
QUADRUPOLE-MOMENTS
CO2 CAPTURE
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Summary:An extremely stable hydrogen-bonded organic framework, HOF-8, was fabricated. HOF-8 is not only thermally stable but also stable in water and common organic solvents. More interestingly, desolvated HOF-8 exhibits high CO2 adsorption as well as highly selective CO2 and C6H6 adsorption at ambient temperature.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0002-7863
1520-5126
1520-5126
DOI:10.1021/ja403002m