A Microporous Hydrogen-Bonded Organic Framework: Exceptional Stability and Highly Selective Adsorption of Gas and Liquid

An extremely stable hydrogen-bonded organic framework, HOF-8, was fabricated. HOF-8 is not only thermally stable but also stable in water and common organic solvents. More interestingly, desolvated HOF-8 exhibits high CO2 adsorption as well as highly selective CO2 and C6H6 adsorption at ambient temp...

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Published inJournal of the American Chemical Society Vol. 135; no. 32; pp. 11684 - 11687
Main Authors Luo, Xu-Zhong, Jia, Xin-Jian, Deng, Ji-Hua, Zhong, Jin-Lian, Liu, Hui-Jin, Wang, Ke-Jun, Zhong, Di-Chang
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 14.08.2013
Amer Chemical Soc
Subjects
Adsorption
ambient temperature
Benzamides - chemistry
Benzene - isolation & purification
carbon dioxide
Carbon Dioxide - isolation & purification
Chemistry
Chemistry, Multidisciplinary
Gases - isolation & purification
Hydrogen Bonding
Models, Molecular
Physical Sciences
Porosity
porous media
Science & Technology
solvents
THERMAL-STABILITY
POROSITY
STORAGE
CARBON-DIOXIDE CAPTURE
HYDROCARBONS
NETWORKS
CRYSTAL
SEPARATION
QUADRUPOLE-MOMENTS
CO2 CAPTURE
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Abstract An extremely stable hydrogen-bonded organic framework, HOF-8, was fabricated. HOF-8 is not only thermally stable but also stable in water and common organic solvents. More interestingly, desolvated HOF-8 exhibits high CO2 adsorption as well as highly selective CO2 and C6H6 adsorption at ambient temperature.
AbstractList An extremely stable hydrogen-bonded organic framework, HOF-8, was fabricated. HOF-8 is not only thermally stable but also stable in water and common organic solvents. More interestingly, desolvated HOF-8 exhibits high CO2 adsorption as well as highly selective CO2 and C6H6 adsorption at ambient temperature.
An extremely stable hydrogen-bonded organic framework, HOF-8, was fabricated. HOF-8 is not only thermally stable but also stable in water and common organic solvents. More interestingly, desolvated HOF-8 exhibits high CO2 adsorption as well as highly selective CO2 and C6H6 adsorption at ambient temperature.An extremely stable hydrogen-bonded organic framework, HOF-8, was fabricated. HOF-8 is not only thermally stable but also stable in water and common organic solvents. More interestingly, desolvated HOF-8 exhibits high CO2 adsorption as well as highly selective CO2 and C6H6 adsorption at ambient temperature.
An extremely stable hydrogen-bonded organic framework, HOF-8, was fabricated. HOF-8 is not only thermally stable but also stable in water and common organic solvents. More interestingly, desolvated HOF-8 exhibits high CO₂ adsorption as well as highly selective CO₂ and C₆H₆ adsorption at ambient temperature.
Author Deng, Ji-Hua
Zhong, Di-Chang
Luo, Xu-Zhong
Liu, Hui-Jin
Jia, Xin-Jian
Zhong, Jin-Lian
Wang, Ke-Jun
AuthorAffiliation Gannan Normal University
AuthorAffiliation_xml – name: Gannan Normal University
Author_xml – sequence: 1
  givenname: Xu-Zhong
  surname: Luo
  fullname: Luo, Xu-Zhong
  email: zhong_dichang@hotmail.com, luoxuzhong@hotmail.com
– sequence: 2
  givenname: Xin-Jian
  surname: Jia
  fullname: Jia, Xin-Jian
– sequence: 3
  givenname: Ji-Hua
  surname: Deng
  fullname: Deng, Ji-Hua
– sequence: 4
  givenname: Jin-Lian
  surname: Zhong
  fullname: Zhong, Jin-Lian
– sequence: 5
  givenname: Hui-Jin
  surname: Liu
  fullname: Liu, Hui-Jin
– sequence: 6
  givenname: Ke-Jun
  surname: Wang
  fullname: Wang, Ke-Jun
– sequence: 7
  givenname: Di-Chang
  surname: Zhong
  fullname: Zhong, Di-Chang
  email: zhong_dichang@hotmail.com, luoxuzhong@hotmail.com
BackLink https://www.ncbi.nlm.nih.gov/pubmed/23885835$$D View this record in MEDLINE/PubMed
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Issue 32
Keywords THERMAL-STABILITY
POROSITY
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CARBON-DIOXIDE CAPTURE
HYDROCARBONS
NETWORKS
CRYSTAL
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QUADRUPOLE-MOMENTS
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Snippet An extremely stable hydrogen-bonded organic framework, HOF-8, was fabricated. HOF-8 is not only thermally stable but also stable in water and common organic...
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SubjectTerms Adsorption
ambient temperature
Benzamides - chemistry
Benzene - isolation & purification
carbon dioxide
Carbon Dioxide - isolation & purification
Chemistry
Chemistry, Multidisciplinary
Gases - isolation & purification
Hydrogen Bonding
Models, Molecular
Physical Sciences
Porosity
porous media
Science & Technology
solvents
Title A Microporous Hydrogen-Bonded Organic Framework: Exceptional Stability and Highly Selective Adsorption of Gas and Liquid
URI http://dx.doi.org/10.1021/ja403002m
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https://www.ncbi.nlm.nih.gov/pubmed/23885835
https://www.proquest.com/docview/1424323207
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