One-Step Fabrication of GeSn Branched Nanowires

• Published in: Chemistry of materials Vol. 31; no. 11; pp. 4016 - 4024
• Main Authors: Doherty, Jessica, Biswas, Subhajit, McNulty, David, Downing, Clive, Raha, Sreyan, O’Regan, Colm, Singha, Achintya, O’Dwyer, Colm, Holmes, Justin D
• Format: Journal Article
• Language: English
• Published: American Chemical Society 11.06.2019
• ISSN: 0897-4756; 1520-5002
• DOI: 10.1021/acs.chemmater.9b00475

We report for the first time the self-catalyzed, single-step growth of branched GeSn nanostructures by a vapor–liquid–solid mechanism. These typical GeSn nanostructures consist of ⟨111⟩-oriented, Sn-rich (∼8 atom %) GeSn “branches” grown epitaxially on GeSn “trunks”, with a Sn content of ∼4 atom %. The trunks were seeded from Au0.80Ag0.20 nanoparticles followed by the catalytic growth of secondary branches (diameter ∼ 50 nm) from the excess of Sn on the sidewalls of the trunks, as determined by high-resolution electron microscopy and energy-dispersive X-ray analysis. The nanowires, with ⟨111⟩-directed GeSn branches oriented at ∼70° to the trunks, have no apparent defects or change in crystal structure at the trunk–branch interface; structural quality is retained at the interface with epitaxial crystallographic relation. The electrochemical performance of these highly ordered GeSn nanostructures was explored as a potential anode material for Li-ion batteries, due to their high surface-to-volume ratio and increased charge carrier pathways. The unique structure of the branched nanowires led to high specific capacities comparable to, or greater than, those of conventional Ge nanowire anode materials and Ge1–x Sn x nanocrystals.