Sodium Methyl Carbonate as an Effective C1 Synthon. Synthesis of Carboxylic Acids, Benzophenones, and Unsymmetrical Ketones

Reported is the synthesis of carboxylic acids, symmetrical ketones, and unsymmetrical ketones with selectivity achieved by exploiting the differential reactivity of sodium methyl carbonate with Grignard and organolithium reagents.

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Bibliographic Details
Published inOrganic letters Vol. 21; no. 11; pp. 3882 - 3885
Main Authors Hurst, Timothy E, Deichert, Julie A, Kapeniak, Lucas, Lee, Roland, Harris, Jesse, Jessop, Philip G, Snieckus, Victor
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 07.06.2019
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
CARBAMATE
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Summary:Reported is the synthesis of carboxylic acids, symmetrical ketones, and unsymmetrical ketones with selectivity achieved by exploiting the differential reactivity of sodium methyl carbonate with Grignard and organolithium reagents.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
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ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.9b00773