Cobalt-Catalyzed Selective Hydrogenation of Nitriles to Secondary Imines

The first example of cobalt-catalyzed selective hydrogenation of nitriles to secondary imines is reported. The results demonstrate the significantly different selectivity compared with the previously reported cobalt catalytic system during the nitrile hydrogenation. A variety of aromatic and aliphat...

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Published inOrganic letters Vol. 20; no. 20; pp. 6430 - 6435
Main Authors Li, Huaifeng, Al-Dakhil, Abdullah, Lupp, Daniel, Gholap, Sandeep Suryabhan, Lai, Zhiping, Liang, Lan-Chang, Huang, Kuo-Wei
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 19.10.2018
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
MILD
SILYLATIVE REDUCTION
PINCER COMPLEXES
HYDROSILYLATION
PRIMARY AMINES
METAL-LIGAND COOPERATION
BOND ACTIVATION
IRON
AROMATIZATION-DEAROMATIZATION
RUTHENIUM COMPLEX
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Summary:The first example of cobalt-catalyzed selective hydrogenation of nitriles to secondary imines is reported. The results demonstrate the significantly different selectivity compared with the previously reported cobalt catalytic system during the nitrile hydrogenation. A variety of aromatic and aliphatic nitriles are hydrogenated to the corresponding secondary imines.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.8b02744