Contact Angle Hysteresis of Microbead Suspensions

• Published in: Langmuir Vol. 26; no. 22; pp. 17082 - 17089
• Main Authors: Waghmare, Prashant R, Mitra, Sushanta K
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 16.11.2010
• Subjects: Chemistry; Exact sciences and technology; General and physical chemistry; Glass - chemistry; Interfaces: Adsorption, Reactions, Films, Forces; Microspheres; Solid-liquid interface; Surface physical chemistry; Surface Tension; Suspensions; Dynamic contact angle; Correlation; Flow rate; Inclusion; Volume fraction; Wetting; Device; Suspension; Contact angle; Equilibrium; Mechanism; Drop; Contact line; Substrate; Wettability; Sessile; Models; Surface tension; Transport; Physicochemical properties; Hysteresis
• ISSN: 0743-7463; 1520-5827
• DOI: 10.1021/la1025526

Microbead suspensions are often used in microfluidic devices for transporting biomolecules. An experimental investigation on the wettability of microbead suspension is presented in this study. The variation in the surface tension and the equilibrium contact angle with the change in the volume fraction of the microbead is presented here. The surface tension of the microbead suspension is measured with the pendant drop technique, whereas the dynamic contact angle measurements, i.e., advancing and receding contact angles, are measured with the sessile drop technique. An equilibrium contact angle of a suspension with particular volume fraction is determined by computing an average over the measured advancing and receding contact angles. It is observed that the surface tension and the equilibrium contact angle determined from advancing and receding contact angles vary with the magnitude of the microbeads volume fraction in the suspension. A decrease in the surface tension with an increase in the volume fraction of the microbead suspension is observed. The advancement and the recession in contact line for dynamic contact angle measurements are achieved with the motorized dosing mechanism. For microbead suspensions, the advancement of the contact line is faster as compared to the recession of the contact line for the same flow rate. The presence of microbeads assists in the advancement and the recession of the contact line of the suspension. A decrease in the equilibrium contact angles with an increase in the microbead suspension volume fraction is observed. Inclusion of microbeads in the suspension increases the wetting capability for the considered combination of the microbead suspension and substrate. Finally, empirical correlations for the surface tension and the contact angle of the suspension as a function of microbead volume fraction are proposed. Such correlations can readily be used to develop mechanistic models for the capillary transport of microbead suspensions related to LOC applications.