Hydrophobic Brønsted Acid−Base Ionic Liquids Based on PAMAM Dendrimers with High Proton Conductivity and Blue Photoluminescence

A simple strategy has been described to synthesize a novel hydrophobic Brønsted acid−base ionic liquid based on a PAMAM dendrimer. The resulting ionic liquid is highly fluorescent and proton conductive with great potential for sensors and nonaqueous proton-conducting electrolytes.

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 127; no. 37; pp. 12784 - 12785
Main Authors Huang, Jing-Fang, Luo, Huimin, Liang, Chengdu, Sun, I−Wen, Baker, Gary A, Dai, Sheng
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 21.09.2005
Subjects
Applied sciences
Dendrimers
Electrochemistry
ELECTROLYTES
Exact sciences and technology
Light
LIQUIDS
Luminescent Measurements
Organic polymers
Photochemistry
PHOTOLUMINESCENCE
Physicochemistry of polymers
PHYSICS OF ELEMENTARY PARTICLES AND FIELDS
Polyamines - chemical synthesis
Polyamines - chemistry
POTENTIALS
Properties and characterization
PROTONS
Solution and gel properties
Solvents - chemistry
Surface Properties
Amidoamine polymer
Alkali metal Compounds
Electrochemical properties
Brönsted acid
Ionic solution
Chemical stability
Photoluminescence
Proton conductivity
Hydrophobic compound
Fluorescence spectrometry
Thermal stability
Dendritic structure
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Summary:A simple strategy has been described to synthesize a novel hydrophobic Brønsted acid−base ionic liquid based on a PAMAM dendrimer. The resulting ionic liquid is highly fluorescent and proton conductive with great potential for sensors and nonaqueous proton-conducting electrolytes.
Bibliography:istex:1D74A416C87A12709BF40EA91B11AE22F35CA73D
ark:/67375/TPS-D5CD8SQ0-S
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
DE-AC05-00OR22725
USDOE National Nuclear Security Administration (NNSA)
ISSN:0002-7863
1520-5126
DOI:10.1021/ja053965x