Spectroelectrochemical Sensing Based on Attenuated Total Internal Reflectance Stripping Voltammetry. 1. Determination of Lead and Cadmium
The electrodeposition and subsequent stripping of lead and cadmium on an indium tin oxide (ITO) optically transparent electrode (OTE) were monitored by attenuated total internal reflectance. Light passing through the ITO-OTE is attenuated proportionally to the concentration of metal ion and depositi...
Saved in:
Published in | Analytical chemistry (Washington) Vol. 75; no. 17; pp. 4585 - 4590 |
---|---|
Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Washington, DC
American Chemical Society
01.09.2003
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Summary: | The electrodeposition and subsequent stripping of lead and cadmium on an indium tin oxide (ITO) optically transparent electrode (OTE) were monitored by attenuated total internal reflectance. Light passing through the ITO-OTE is attenuated proportionally to the concentration of metal ion and deposition time. The wavelength dependence of the optical responses of deposited Pb and Cd was determined; optimal performance based on maximum sensor absorbance was at 750 nm for Pb and at 400 nm for Cd. Calibration curves were obtained over a range of 5 × 10-8 to 5 × 10-5 M and 1 × 10-9 to 1 × 10-5 M for Pb and Cd, respectively, using change in absorbance that accompanied deposition and subsequent stripping of the electrodeposited metal from the ITO. |
---|---|
Bibliography: | istex:44C6F88789B3F7DD12AE848E057CA5AFCB45746F ark:/67375/TPS-WS74F9JS-X ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0003-2700 1520-6882 |
DOI: | 10.1021/ac034281f |