Polymerization of Methylenecyclohexanes Catalyzed by Diimine–Pd Complex. Polymers Having trans- or cis-1,4- and trans-1,3-Cyclohexylene Groups
Diimine–Pd complex promotes isomerization polymerization of methylenecyclohexane and 4-alkyl-1-methylenecyclohexanes to afford the polymers which contain trans- and cis-1,4-cyclohexylene groups, respectively, along the polymer chain. The polymerization of 3-methyl-1-methylenecyclohexane yields the p...
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| Published in | Organometallics Vol. 34; no. 12; pp. 3007 - 3011 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
American Chemical Society
22.06.2015
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| Online Access | Get full text |
| ISSN | 0276-7333 1520-6041 |
| DOI | 10.1021/acs.organomet.5b00313 |
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| Abstract | Diimine–Pd complex promotes isomerization polymerization of methylenecyclohexane and 4-alkyl-1-methylenecyclohexanes to afford the polymers which contain trans- and cis-1,4-cyclohexylene groups, respectively, along the polymer chain. The polymerization of 3-methyl-1-methylenecyclohexane yields the polymer having trans-1,3-cyclohexylene groups. DSC measurement of a part of the polymers revealed their glass transition at high temperature (T g = 162 and 201 °C). |
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| AbstractList | Diimine–Pd complex promotes isomerization polymerization of methylenecyclohexane and 4-alkyl-1-methylenecyclohexanes to afford the polymers which contain trans- and cis-1,4-cyclohexylene groups, respectively, along the polymer chain. The polymerization of 3-methyl-1-methylenecyclohexane yields the polymer having trans-1,3-cyclohexylene groups. DSC measurement of a part of the polymers revealed their glass transition at high temperature (T g = 162 and 201 °C). |
| Author | Watanabe, Keisuke Osakada, Kohtaro Sogo, Kenji Takeuchi, Daisuke |
| AuthorAffiliation | Chemical Resources Laboratory R1-04 Sumitomo Chemical Co. Ltd Petrochemical Research Laboratory Tokyo Institute of Technology |
| AuthorAffiliation_xml | – name: Chemical Resources Laboratory R1-04 – name: Sumitomo Chemical Co. Ltd – name: Petrochemical Research Laboratory – name: Tokyo Institute of Technology |
| Author_xml | – sequence: 1 givenname: Daisuke surname: Takeuchi fullname: Takeuchi, Daisuke email: dtakeuch@res.titech.ac.jp – sequence: 2 givenname: Keisuke surname: Watanabe fullname: Watanabe, Keisuke – sequence: 3 givenname: Kenji surname: Sogo fullname: Sogo, Kenji – sequence: 4 givenname: Kohtaro surname: Osakada fullname: Osakada, Kohtaro |
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| CitedBy_id | crossref_primary_10_1021_acs_macromol_4c01663 crossref_primary_10_1246_cl_200793 crossref_primary_10_1002_ange_201700546 crossref_primary_10_1016_j_eurpolymj_2022_111022 crossref_primary_10_1016_j_tetlet_2019_07_029 crossref_primary_10_1021_acs_organomet_7b00783 crossref_primary_10_1038_s41428_018_0073_3 crossref_primary_10_1021_acs_macromol_5b01458 crossref_primary_10_1038_s41428_019_0260_x crossref_primary_10_1002_anie_201700546 crossref_primary_10_1007_s10118_019_2183_6 crossref_primary_10_1021_jacs_5b10804 crossref_primary_10_1016_j_polymer_2015_09_077 crossref_primary_10_1039_C8PY00047F crossref_primary_10_2472_jsms_68_47 crossref_primary_10_1246_cl_151138 crossref_primary_10_1002_mame_202400358 crossref_primary_10_1021_acs_organomet_9b00150 |
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| Title | Polymerization of Methylenecyclohexanes Catalyzed by Diimine–Pd Complex. Polymers Having trans- or cis-1,4- and trans-1,3-Cyclohexylene Groups |
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