Polymerization of Methylenecyclohexanes Catalyzed by Diimine–Pd Complex. Polymers Having trans- or cis-1,4- and trans-1,3-Cyclohexylene Groups
Diimine–Pd complex promotes isomerization polymerization of methylenecyclohexane and 4-alkyl-1-methylenecyclohexanes to afford the polymers which contain trans- and cis-1,4-cyclohexylene groups, respectively, along the polymer chain. The polymerization of 3-methyl-1-methylenecyclohexane yields the p...
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Published in | Organometallics Vol. 34; no. 12; pp. 3007 - 3011 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
American Chemical Society
22.06.2015
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Online Access | Get full text |
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Summary: | Diimine–Pd complex promotes isomerization polymerization of methylenecyclohexane and 4-alkyl-1-methylenecyclohexanes to afford the polymers which contain trans- and cis-1,4-cyclohexylene groups, respectively, along the polymer chain. The polymerization of 3-methyl-1-methylenecyclohexane yields the polymer having trans-1,3-cyclohexylene groups. DSC measurement of a part of the polymers revealed their glass transition at high temperature (T g = 162 and 201 °C). |
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ISSN: | 0276-7333 1520-6041 |
DOI: | 10.1021/acs.organomet.5b00313 |