Engineering Schottky Contacts in Open-Air Fabricated Heterojunction Solar Cells to Enable High Performance and Ohmic Charge Transport

• Published in: ACS applied materials & interfaces Vol. 6; no. 24; pp. 22192 - 22198
• Main Authors: Hoye, Robert L. Z, Heffernan, Shane, Ievskaya, Yulia, Sadhanala, Aditya, Flewitt, Andrew, Friend, Richard H, MacManus-Driscoll, Judith L, Musselman, Kevin P
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 24.12.2014
• Subjects: Cu2O solar cells; electrochemical deposition; spatial atmospheric atomic layer deposition; zinc magnesium oxide; Schottky barrier
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/am5058663

The efficiencies of open-air processed Cu2O/Zn1–x Mg x O heterojunction solar cells are doubled by reducing the effect of the Schottky barrier between Zn1–x Mg x O and the indium tin oxide (ITO) top contact. By depositing Zn1–x Mg x O with a long band-tail, charge flows through the Zn1–x Mg x O/ITO Schottky barrier without rectification by hopping between the sub-bandgap states. High current densities are obtained by controlling the Zn1–x Mg x O thickness to ensure that the Schottky barrier is spatially removed from the p–n junction, allowing the full built-in potential to form, in addition to taking advantage of the increased electrical conductivity of the Zn1–x Mg x O films with increasing thickness. This work therefore shows that the Zn1–x Mg x O window layer sub-bandgap state density and thickness are critical parameters that can be engineered to minimize the effect of Schottky barriers on device performance. More generally, these findings show how to improve the performance of other photovoltaic system reliant on transparent top contacts, e.g., CZTS and CIGS.