Lanthanide Upconverted Luminescence for Simultaneous Contactless Optical Thermometry and Manometry–Sensing under Extreme Conditions of Pressure and Temperature

• Published in: ACS applied materials & interfaces Vol. 12; no. 36; pp. 40475 - 40485
• Main Authors: Goderski, Szymon, Runowski, Marcin, Woźny, Przemysław, Lavín, Víctor, Lis, Stefan
• Format: Journal Article
• Language: English
• Published: American Chemical Society 09.09.2020
• Subjects: Functional Inorganic Materials and Devices; upconversion emission in lanthanide-doped materials; bifunctional luminescence thermometer−manometer; noncontact optical pressure and temperature sensors; micron-sized YF3:Yb3+-Er3+ particles
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/acsami.0c09882

The growing interest in the miniaturization of various devices and conducting experiments under extreme conditions of pressure and temperature causes the need for the development of small, contactless, precise, and accurate optical sensors without any electrical connections. In this work, YF3:Yb3+-Er3+ upconverting microparticles are used as a bifunctional luminescence sensor for simultaneous temperature and pressure measurements. Different changes in the properties of Er3+ green and red upconverted luminescence, after excitation of Yb3+ ions in the near-infrared at ∼975 nm, are used to calibrate pressure and/or temperature inside the hydrostatic chamber of a diamond anvil cell (DAC). For temperature sensing, changes in the relative intensities of the Er3+ green upconverted luminescence of 2H11/2 and 4S3/2 thermally coupled multiplets to the 4I15/2 ground state, whose relative populations follow a Boltzmann distribution, are calibrated. For pressure sensing, the spectral shift of the Er3+ upconverted red emission peak at ∼665 nm, between the Stark sublevels of the 4F9/2 → 4I15/2 transition, is used. Experiments performed under simultaneous extreme conditions of pressure, up to ∼8 GPa, and temperature, up to ∼473 K, confirm the possibility of remote optical pressure and temperature sensing.