Direct Vapor–Liquid–Solid Synthesis of All-Inorganic Perovskite Nanowires for High-Performance Electronics and Optoelectronics

• Published in: ACS nano Vol. 13; no. 5; pp. 6060 - 6070
• Main Authors: Meng, You, Lan, Changyong, Li, Fangzhou, Yip, SenPo, Wei, Renjie, Kang, Xiaolin, Bu, Xiuming, Dong, Ruoting, Zhang, Heng, Ho, Johnny C
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 28.05.2019
• Subjects: vapor−liquid−solid; electronic; all-inorganic; optoelectronic; perovskite; nanowire
• ISSN: 1936-0851; 1936-086X
• DOI: 10.1021/acsnano.9b02379

Controlled synthesis of lead halide perovskite (LHP) nanostructures not only benefits fundamental research but also offers promise for applications. Among many synthesis techniques, although catalytic vapor–liquid–solid (VLS) growth is recognized as an effective route to achieve high-quality nanostructures, until now, there is no detailed report on VLS grown LHP nanomaterials due to the emerging challenges in perovskite synthesis. Here, we develop a direct VLS growth for single-crystalline all-inorganic lead halide perovskite (i.e., CsPbX3; X = Cl, Br, or I) nanowires (NWs). These NWs exhibit high-performance photodetection with the responsivity exceeding 4489 A/W and detectivity over 7.9 × 1012 Jones toward the visible light regime. Field-effect transistors (FET) based on individual CsPbX3 NWs are also fabricated, where they show the superior hole mobility of up to 3.05 cm2/(V s), higher than other all-inorganic LHP devices. This work provides important guidelines for the further improvement of these perovskite nanostructures for utilizations.