Trapping Structural Coloration by a Bioinspired Gyroid Microstructure in Solid State

• Published in: ACS nano Vol. 12; no. 1; pp. 485 - 493
• Main Authors: Lin, En-Li, Hsu, Wei-Lun, Chiang, Yeo-Wan
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 23.01.2018
• Subjects: block copolymers; structural coloration; photonic crystals; gyroid; trapping
• ISSN: 1936-0851; 1936-086X
• DOI: 10.1021/acsnano.7b07017

In theory, gyroid photonic crystals in butterfly wings exhibit advanced optical properties as a result of their highly interconnected microstructures. Because of the difficulties in synthesizing artificial gyroid materials having periodicity corresponding to visible wavelengths, human-made visible gyroid photonic crystals are still unachievable by self-assembly. In this study, we develop a physical approachtrapping of structural coloration (TOSC)through which the visible structural coloration of an expanded gyroid lattice in a solvated state can be preserved in the solid state, thereby allowing the fabrication of visible-wavelength gyroid photonic crystals. Through control over the diffusivity and diffusive distance for solvent evaporation, the single-molecular-weight gyroid block copolymer photonic crystal can exhibit desired structural coloration in the solid state without the need to introduce any additives, namely, evapochromism. Also, greatly enhanced reflectivity is observed arising from the formation of porous gyroid nanochannels, similar to those in butterfly wings. As a result, TOSC facilitates the fabrication of the human-made solid gyroid photonic crystal featuring tunable and switchable structural coloration without the synthesis to alter the molecular weight. It appears to be applicable in the fields of optical communication, energy, light-emission, sensors, and displays.