Ultrafast Nuclear Magnetic Resonance as a Tool to Detect Rapid Chemical Change in Solution

Ultrafast nuclear magnetic resonance (NMR) uses spatial encoding to record an entire two-dimensional data set in just a single scan. The approach can be applied to either Fourier-transform or Laplace-transform NMR. In both cases, acquisition times are significantly shorter than traditional 2D/Laplac...

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Bibliographic Details
Published inACS Physical Chemistry Au Vol. 4; no. 5; pp. 453 - 463
Main Authors Tickner, Ben. J., Singh, Kawarpal, Zhivonitko, Vladimir V., Telkki, Ville-Veikko
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 25.09.2024
Subjects
spatial-encoding
Ultrafast
magnetic resonance
reactivity
hyperpolarization
Laplace
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Summary:Ultrafast nuclear magnetic resonance (NMR) uses spatial encoding to record an entire two-dimensional data set in just a single scan. The approach can be applied to either Fourier-transform or Laplace-transform NMR. In both cases, acquisition times are significantly shorter than traditional 2D/Laplace NMR experiments, which allows them to be used to monitor rapid chemical transformations. This Perspective outlines the principles of ultrafast NMR and focuses on examples of its use to detect fast molecular conversions in situ with high temporal resolution. We discuss how this valuable tool can be applied in the future to study a much wider variety of novel reactivity.
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ISSN:2694-2445
2694-2445
DOI:10.1021/acsphyschemau.4c00042