Oscillations and pattern formation during electrodeposition of lead metal in batch and flow reactors

Cathode potential changes with time during the process of electrodeposition of lead metal from its aqueous solutions in batch reactor as well as in a continuously stirred tank reactor (CSTR) have been reported. Growth kinetics at constant current /potential has been studied for correlation. Influenc...

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Bibliographic Details
Published inJournal of physical chemistry (1952) Vol. 97; no. 18; pp. 4871 - 4876
Main Authors Rastogi, R. P, Das, Ishwar, Pushkarna, Anal, Chand, Sudha
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 01.05.1993
Subjects
Chemistry
Electrochemistry
Electrodeposition
Exact sciences and technology
General and physical chemistry
Study of interfaces
Electrolyte solution
Growth
Instrumentation
Kinetic method
Transition metal
Tree structure
Acetate
Electroplating
Experimental study
Continuous stirred tank reactor
Electrochemical reactor
Electrodes
Continuous wave
Platinum
Concentration effect
Equivalent circuit
Lead
Electrical conductance
Aqueous solution
Electrode potential
Dendritic structure
Oscillating reaction
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Summary:Cathode potential changes with time during the process of electrodeposition of lead metal from its aqueous solutions in batch reactor as well as in a continuously stirred tank reactor (CSTR) have been reported. Growth kinetics at constant current /potential has been studied for correlation. Influence of electrolyte concentration, applied current and certain polymer additives on morphologies, and oscillatory characteristics have been investigated.
Bibliography:istex:AADBCF680D79A85100A3ABE52D1C863B5942C51B
ark:/67375/TPS-4KSTB42Z-C
ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ISSN:0022-3654
1541-5740
DOI:10.1021/j100120a046