Hierarchical Carbon Nanotube-Coated Carbon Fiber: Ultra Lightweight, Thin, and Highly Efficient Microwave Absorber

• Published in: ACS applied materials & interfaces Vol. 10; no. 29; pp. 24816 - 24828
• Main Authors: Singh, Sandeep Kumar, Akhtar, Mohammad Jaleel, Kar, Kamal K
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 25.07.2018
• Subjects: trapping center; complex permittivity; carbon nanotube-coated carbon fiber (CNTCF); microwave absorption; multiple reflection
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/acsami.8b06673

Strong EM wave absorption and lightweight are the foremost important factors that drive the real-world applications of the modern microwave absorbers. This work mainly deals with the design of highly efficient microwave absorbers, where a hierarchical carbon nanotube (CNT) forest is first grown on the carbon fiber (CF) through the catalytic chemical vapor deposition method. The hierarchical carbon nanotube grown on the carbon fiber (CNTCF) is then embedded in the epoxy matrix to synthesize lightweight nanocomposites for their use as efficient microwave absorbers. The morphological study shows that carbon nanotubes (CNTs) self-assemble to form a trapping center on the carbon fiber. The electromagnetic characteristics of resultant nanocomposites are investigated exclusively in the X-band (8.2–12.4 GHz) using the network analyzer. The synthesized nanocomposites, containing 0.35 and 0.50 wt % CNTCFs, exhibit excellent microwave absorption properties, which could be attributed to the better impedance matching conditions and high dielectric losses. The reflection loss (RL) of −42.0 dB (99.99% absorption) with −10 dB (90% absorption) and −20 dB (99% absorption) bandwidths of 2.7 and 1.16 GHz, respectively, is achieved for 0.35 wt % CNTCF loading at 2.5 mm thickness. The composite with 0.50 wt % CNTCF loading illustrates substantial absorption efficiency with the RL reaching −24.5 dB (99.65% absorption) at 9.8 GHz and −10 dB bandwidth comprising 84.5% of the entire X band. The excellent microwave properties obtained here are primarily due to the electric dipole polarization, interfacial polarization, and unique trapping center. These trapping centers basically induce multiple reflections and scatterings, which attenuate more microwave energy. This investigation opens a new approach for the development of extremely lightweight, small-thickness, and highly efficient microwave absorbers for X-band applications.