1,1‘-Diisocyanoferrocene and a Convenient Synthesis of Ferrocenylamine

The new ferrocene derivative 1,1‘-diisocyanoferrocene was prepared in 50% isolated yield from the reaction of 1,1‘-diisocyanatoferrocene with formic acid followed by thermal decarboxylation and reaction with POCl3/NH(i-Pr)2. An improved synthesis route to ferrocenylamine involves lithiation of ferro...

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Bibliographic Details
Published inOrganometallics Vol. 20; no. 1; pp. 224 - 226
Main Authors van Leusen, Daan, Hessen, Bart
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 08.01.2001
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Inorganic & Nuclear
Chemistry, Organic
Physical Sciences
Science & Technology
DERIVATIVES
RING-OPENING POLYMERIZATION
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Summary:The new ferrocene derivative 1,1‘-diisocyanoferrocene was prepared in 50% isolated yield from the reaction of 1,1‘-diisocyanatoferrocene with formic acid followed by thermal decarboxylation and reaction with POCl3/NH(i-Pr)2. An improved synthesis route to ferrocenylamine involves lithiation of ferrocene with t-BuLi followed by reaction with α-azidostyrene and subsequent acidification.
Bibliography:Netherlands Institute for Catalysis Research (NIOK) Publication no. RUG-00-4-4.
istex:CEDA82DAB089B73C20B6554E6C150DE3F3B60FBB
ark:/67375/TPS-93SJLJH8-Z
ISSN:0276-7333
1520-6041
DOI:10.1021/om000678n