Total synthesis of (-)-urdamycinone B through polyketide condensation

(-)-Urdamycinone B, the enantiomer of a natural antitumor antibiotic, was synthesized by employing polyketide condensation reactions.

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Bibliographic Details
Published inJournal of organic chemistry Vol. 57; no. 6; pp. 1647 - 1649
Main Authors Yamaguchi, Masahiko, Okuma, Tadashi, Horiguchi, Akira, Ikeura, Chinatsu, Minami, Toru
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 01.03.1992
Amer Chemical Soc
Subjects
Alicyclic compounds
Alicyclic compounds, terpenoids, prostaglandins, steroids
Chemistry
Chemistry, Organic
Exact sciences and technology
Organic chemistry
Physical Sciences
Preparations and properties
Science & Technology
MICROORGANISMS
VINEOMYCIN-A1
ANGUCYCLINE ANTIBIOTICS
METABOLIC PRODUCTS
URDAMYCIN-A
AQUAYAMYCIN
STREPTOMYCES-FRADIAE
INHIBITOR
Antineoplastic agent
Antibiotic
Enantiomer
Quinone
Ketol
Phenols
Aromatic compound
Tetracyclic compound
C-Glycoside
Total synthesis
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Summary:(-)-Urdamycinone B, the enantiomer of a natural antitumor antibiotic, was synthesized by employing polyketide condensation reactions.
Bibliography:istex:2669B22ED540558FEFAA9D7592FF9A04C2F516F6
ark:/67375/TPS-5M1XFDNL-8
ISSN:0022-3263
1520-6904
DOI:10.1021/jo00032a009