Preparation and characterization of crystalline N-acylammonium salts

The reaction of a tertiary amine with an acid chloride or chloroformate followed by anion exchange with either sodium tetraphenylborate or silver tetrafluoroborate provides stable, nonhygroscopic, crystalline acylammonium salts.

Saved in:
Bibliographic Details
Published inJournal of organic chemistry Vol. 57; no. 19; pp. 5136 - 5139
Main Authors King, Joseph A, Bryant, Garold L
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 01.09.1992
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Exact sciences and technology
Organic chemistry
Physical Sciences
Science & Technology
2,4-DINITROPHENYL ACETATE
1,2-DIHYDROPYRIDINES
ACYL CHLORIDES
ISOQUINOLINE
METHOXYCARBONYL GROUP
NUCLEOFUGALITIES
IONS
INTERMEDIATE
CHLOROFORMATE
SUBSTITUTED PYRIDINES
Tertiary amine
Acyl halide
Acetonitrile
Crystalline state
Online AccessGet full text

Cover

More Information
Summary:The reaction of a tertiary amine with an acid chloride or chloroformate followed by anion exchange with either sodium tetraphenylborate or silver tetrafluoroborate provides stable, nonhygroscopic, crystalline acylammonium salts.
Bibliography:ark:/67375/TPS-496GMJ8W-4
istex:5D67C3DB67F34ACF2B8DCC0D19F333B34C46691F
ISSN:0022-3263
1520-6904
DOI:10.1021/jo00045a025