Strong effect of liquid Fe–S on elastic wave velocity of olivine aggregate: Implication for the low velocity anomaly at the base of the lunar mantle

• Published in: Earth and planetary science letters Vol. 618; no. C; p. 118287
• Main Authors: Kono, Yoshio, Kuwahara, Hideharu, Gréaux, Steeve, Rivers, Mark L., Wang, Yanbin, Higo, Yuji, Mitsu, Keisuke, Kondo, Nozomi
• Format: Journal Article
• Language: English
• Published: United States Elsevier B.V 15.09.2023; Elsevier
• Subjects: elastic wave velocity; Geochemistry & Geophysics; high pressure; liquid Fe–S; lunar mantle; microtomography; lunar mantle; high pressure; liquid Fe–S; elastic wave velocity; microtomography
• ISSN: 0012-821X; 1385-013X
• DOI: 10.1016/j.epsl.2023.118287

The origin of the seismic low velocity zone (LVZ) observed at the base of the lunar mantle is important for understanding the nature of the lunar mantle. Liquid Fe–S is considered as a possible candidate of the cause of the LVZ. However, effect of liquid Fe–S on elastic wave velocity of mantle rock has been considered to be minor, according to theoretical estimation based on the high dihedral angle of liquid Fe–S in olivine aggregate observed in previous microstructural analysis of polished sample cross sections. Here we carry out direct measurements of elastic wave velocities of liquid Fe–S-bearing olivine aggregate and report strong reduction of the elastic wave velocities in the presence of liquid Fe–S. The effects of liquid Fe–S in olivine aggregates are much more pronounced than the theoretical estimation. Three-dimensional X-ray microtomography analysis reveals that the geometry of liquid Fe–S strongly depends on the size, with larger liquid Fe–S blobs having low aspect ratios, which may predominantly affect elastic wave velocity. Since smaller spherical Fe–S blobs are much more abundant than the larger elongated blobs, conventional dihedral angle analyses based on scanning electron microscope images tend to statistically over-sample smaller blobs and under-sample larger blobs. Our results suggest that the LVZ at the base of the lunar mantle can be explained by the presence of 4.3–5.0 vol.% liquid Fe–S. The LVZ may be a hidden reservoir of highly siderophile elements (HSEs), which may explain the low abundance of HSEs in the lunar mantle compared to the Earth. •Measurement of effect of liquid Fe–S on Vp and Vs of olivine aggregate.•Stronger reduction of Vp and Vs by liquid Fe–S than theoretical estimation.•3D X-ray microtomography reveals that liquid pore geometry depends on the size.•Large size of liquid Fe–S with small aspect ratio predominantly affects Vp and Vs.•4.3–5.0 vol.% liquid Fe–S can explain the low velocity zone in the lunar mantle.