Photopolymerization Kinetics of Methacrylate Dental Resins

• Published in: Macromolecules Vol. 36; no. 16; pp. 6043 - 6053
• Main Authors: Dickens, S. H, Stansbury, J. W, Choi, K. M, Floyd, C. J. E
• Format: Journal Article
• Language: English
• Published: Washington, DC American Chemical Society 12.08.2003
• Subjects: Applied sciences; Exact sciences and technology; Physicochemistry of polymers; Polymerization; Polymers and radiations; Bifunctional compound; Mass copolymerization; Experimental study; Reaction rate; Crosslinked copolymer; Dental restoration; Biomaterial; Kinetics; Methacrylate copolymer; Monomer; Chemical reactivity; Photochemical copolymerization; Hydrogen bond
• ISSN: 0024-9297; 1520-5835
• DOI: 10.1021/ma021675k

The photopolymerization kinetics of typical dental dimethacrylate monomers were studied by differential photocalorimetry. Increasing proportions of the low-viscosity diluent monomer triethylene glycol dimethacrylate (TEGDMA) were added to either Bis-GMA (2,2-bis[p-(2‘-hydroxy-3‘-methacryloxypropoxy)phenylene]propane), EBADMA (ethoxylated bisphenol A dimethacrylate), or UDMA (1,6-bis(methacryloxy-2-ethoxycarbonylamino)-2,4,4-trimethylhexane) to provide three base resins that differed in their hydrogen-bonding potential and, therefore, resulted in compositions covering a broad range of viscosities. When compared at similar diluent concentrations, UDMA resins were significantly more reactive than Bis-GMA and EBADMA resins. At higher diluent concentrations, EBADMA resins provided the lowest photopolymerization reactivities. Optimum reactivities in the UDMA and EBADMA resin systems were obtained with the addition of relatively small amounts of TEGDMA, whereas the Bis-GMA/TEGDMA resin system required near equivalent mole ratios for highest reactivity. The hydrogen-bonding interactions, which substantially influence the Bis-GMA and UDMA resin series, were examined by Fourier transform infrared spectroscopy and resin viscosity. Synergistic effects of base and diluent monomer on the polymerization rate and the final conversion were found for the two base resins having hydrogen-bonding interactions. The structures of the individual monomers and, consequently, the resin viscosities of the comonomer mixtures strongly influence both the rate and the extent of conversion of the photopolymerization process.