Linear and Two-Photon Photophysical Properties of a Series of Symmetrical Diphenylaminofluorenes
A series of linear, symmetrical, diphenylaminofluorene-based materials are reported. The series investigated was model 9,9-didecyl-2,7-bis(N,N-diphenylamino)fluorene (1), oligomer 9,9-didecyl-N,N-bis(9,9-didecyl-7-N,N-diphenylaminofluoren-2-yl)-N, N-diphenyl-fluorene-2,7-diamine (2), and poly(9,9-di...
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Published in | Chemistry of materials Vol. 16; no. 11; pp. 2267 - 2273 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
Washington, DC
American Chemical Society
01.06.2004
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Subjects | |
Online Access | Get full text |
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Summary: | A series of linear, symmetrical, diphenylaminofluorene-based materials are reported. The series investigated was model 9,9-didecyl-2,7-bis(N,N-diphenylamino)fluorene (1), oligomer 9,9-didecyl-N,N-bis(9,9-didecyl-7-N,N-diphenylaminofluoren-2-yl)-N, N-diphenyl-fluorene-2,7-diamine (2), and poly(9,9-didecyl-2,7-diphenylaminofluorene) (3). Structural characterization and photophysical properties, including linear absorption, quantum yields, single photon fluorescence, and two-photon absorption (2PA) spectra, were studied in polar and nonpolar solvents. 2PA spectra were determined by two independent methods: a nonlinear transmission method employing a femtosecond white-light continuum (WLC) and a two-photon fluorescence (2PF) method. Polymer 3, a low-molecular-weight polymer with fourteen fluorene units, exhibited a very large two-photon absorption cross-section of 17 200 and 6800 × 10-50 cm4 s photon-1 molecule-1 as estimated from the WLC and 2PF methods, respectively. |
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Bibliography: | istex:804C79CF697A5973CAD6B801A91F8F7711E1FAB7 ark:/67375/TPS-318TKFQ3-7 |
ISSN: | 0897-4756 1520-5002 |
DOI: | 10.1021/cm035253g |