Synthesis of a Mechanically Planar Chiral and Axially Chiral [2]Rotaxane

In this study, we synthesized a [2]­rotaxane that was both mechanically planar chiral and axially chiral, comprising a symmetrical bis-crown ether featuring a biphenyl moiety (as the macrocyclic component) and a symmetrical bis-ammonium salt (as the dumbbell-shaped component).

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Bibliographic Details
Published inOrganic letters Vol. 23; no. 22; pp. 8678 - 8682
Main Authors Tajima, Shinya, Muranaka, Atsuya, Naito, Masaya, Taniguch, Noriho, Harada, Mei, Miyagawa, Shinobu, Ueda, Masahiro, Takaya, Hikaru, Kobayashi, Nagao, Uchiyama, Masanobu, Tokunaga, Yuji
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 19.11.2021
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
CATENANES
ROTAXANES
RESOLUTION
STRATEGIES
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Summary:In this study, we synthesized a [2]­rotaxane that was both mechanically planar chiral and axially chiral, comprising a symmetrical bis-crown ether featuring a biphenyl moiety (as the macrocyclic component) and a symmetrical bis-ammonium salt (as the dumbbell-shaped component).
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.1c02983