Designing a Multifunctional Catalyst for the Direct Production of Gasoline-Range Isoparaffins from CO2

• Published in: JACS Au Vol. 1; no. 11; pp. 1961 - 1974
• Main Authors: Dokania, Abhay, Ould-Chikh, Samy, Ramirez, Adrian, Cerrillo, Jose Luis, Aguilar, Antonio, Russkikh, Artem, Alkhalaf, Ahmed, Hita, Idoia, Bavykina, Anastasiya, Shterk, Genrikh, Wehbe, Nimer, Prat, Alain, Lahera, Eric, Castaño, Pedro, Fonda, Emiliano, Hazemann, Jean-Louis, Gascon, Jorge
• Format: Journal Article
• Language: English
• Published: American Chemical Society 22.11.2021
• Subjects: zeolite catalysis; methanol synthesis; reactor engineering; operando characterization; XAS; zeolite modification; CO2 hydrogenation
• ISSN: 2691-3704; 2691-3704
• DOI: 10.1021/jacsau.1c00317

The production of carbon-neutral fuels from CO2 presents an avenue for causing an appreciable effect in terms of volume toward the mitigation of global carbon emissions. To that end, the production of isoparaffin-rich fuels is highly desirable. Here, we demonstrate the potential of a multifunctional catalyst combination, consisting of a methanol producer (InCo) and a Zn-modified zeolite beta, which produces a mostly isoparaffinic hydrocarbon mixture from CO2 (up to ∼85% isoparaffin selectivity among hydrocarbons) at a CO2 conversion of >15%. The catalyst combination was thoroughly characterized via an extensive complement of techniques. Specifically, operando X-ray absorption spectroscopy (XAS) reveals that Zn (which plays a crucial role of providing a hydrogenating function, improving the stability of the overall catalyst combination and isomerization performance) is likely present in the form of Zn6O6 clusters within the zeolite component, in contrast to previously reported estimations.