Scalable Transfer of Suspended Two-Dimensional Single Crystals

• Published in: Nano letters Vol. 15; no. 8; pp. 5089 - 5097
• Main Authors: Li, Bo, He, Yongmin, Lei, Sidong, Najmaei, Sina, Gong, Yongji, Wang, Xin, Zhang, Jing, Ma, Lulu, Yang, Yingchao, Hong, Sanghyun, Hao, Ji, Shi, Gang, George, Antony, Keyshar, Kunttal, Zhang, Xiang, Dong, Pei, Ge, Liehui, Vajtai, Robert, Lou, Jun, Jung, Yung Joon, Ajayan, Pulickel M
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 12.08.2015
• Subjects: Architecture; Graphene; Molybdenum disulfide; Nanostructure; Printing; Silicon substrates; Silver; Two dimensional; van der Waals layered materials; two-dimensional materials; suspended architectures; nanopatterned substrates; Wet-contact printing; capillary-force-free transfer
• ISSN: 1530-6984; 1530-6992
• DOI: 10.1021/acs.nanolett.5b01210

Large-scale suspended architectures of various two-dimensional (2D) materials (MoS2, MoSe2, WS2, and graphene) are demonstrated on nanoscale patterned substrates with different physical and chemical surface properties, such as flexible polymer substrates (polydimethylsiloxane), rigid Si substrates, and rigid metal substrates (Au/Ag). This transfer method represents a generic, fast, clean, and scalable technique to suspend 2D atomic layers. The underlying principle behind this approach, which employs a capillary-force-free wet-contact printing method, was studied by characterizing the nanoscale solid–liquid–vapor interface of 2D layers with respect to different substrates. As a proof-of-concept, a photodetector of suspended MoS2 has been demonstrated with significantly improved photosensitivity. This strategy could be extended to several other 2D material systems and open the pathway toward better optoelectronic and nanoelectromechnical systems.