Lanthanide–Organic Coordination Frameworks Showing New 5‑Connected Network Topology and 3D Ordered Array of Single-Molecular Magnet Behavior in the Dy Case

Five isostructural lanthanide–organic coordination frameworks with a unique 3-D 5-connected (47.63)­(43.65.​82) network, namely, [Ln(phen)­(L)] n (Ln = Dy for 1, Gd for 2, Ho for 3, Er for 4, and Tb for 5), have been prepared based on bridging 5-hydroxyisophthalic acid (H3 L) and chelating 1,10-phen...

Full description

Saved in:
Bibliographic Details
Published inInorganic chemistry Vol. 53; no. 13; pp. 6708 - 6714
Main Authors Chen, Min, Sañudo, E. Carolina, Jiménez, Erika, Fang, Shao-Ming, Liu, Chun-Sen, Du, Miao
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 07.07.2014
Online AccessGet full text

Cover

More Information
Summary:Five isostructural lanthanide–organic coordination frameworks with a unique 3-D 5-connected (47.63)­(43.65.​82) network, namely, [Ln(phen)­(L)] n (Ln = Dy for 1, Gd for 2, Ho for 3, Er for 4, and Tb for 5), have been prepared based on bridging 5-hydroxyisophthalic acid (H3 L) and chelating 1,10-phenanthroline (phen) coligand. Significantly, the Dy(III) complex 1 is an organized array of single-molecular magnets (SMMs), with frequency-dependent out-of-phase ac susceptibility signals and magnetization hysteresis at 4 K. Further analysis of the magnetic results can reveal that the SMM behavior of 1 should arise from the smaller ferromagnetic interaction between the Dy(III) ions. Complex 1 was also characterized by X-ray absorption spectra, which give the clear X-ray magnetic circular dichroism signal.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0020-1669
1520-510X
1520-510X
DOI:10.1021/ic500490x