One-Step Construction of Two Different Kinds of Pores in a 2D Covalent Organic Framework

Covalent organic frameworks (COFs) are crystalline porous materials bearing microporous or mesoporous pores. The type and size of pores play crucial roles in regulating the properties of COFs. In this work, a novel COF, which bears two different kinds of ordered pores with controllable sizes: one wi...

Full description

Saved in:
Bibliographic Details
Published inJournal of the American Chemical Society Vol. 136; no. 45; pp. 15885 - 15888
Main Authors Zhou, Tian-You, Xu, Shun-Qi, Wen, Qiang, Pang, Zhong-Fu, Zhao, Xin
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 12.11.2014
Online AccessGet full text

Cover

More Information
Summary:Covalent organic frameworks (COFs) are crystalline porous materials bearing microporous or mesoporous pores. The type and size of pores play crucial roles in regulating the properties of COFs. In this work, a novel COF, which bears two different kinds of ordered pores with controllable sizes: one within microporous range (7.1 Å) and the other in mesoporous range (26.9 Å), has been constructed via one-step synthesis. The structure of the dual-pore COF was confirmed by PXRD investigation, nitrogen adsorption–desorption study, and theoretical calculations.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0002-7863
1520-5126
DOI:10.1021/ja5092936