CH Activation with an O-Donor Iridium−Methoxo Complex

A thermally and air stable O-donor, iridium−methoxo complex is reported that undergoes stoichiometric, intermolecular C−H activation of benzene with co-generation of methanol and the iridium−phenyl complex.

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Bibliographic Details
Published inJournal of the American Chemical Society Vol. 127; no. 41; pp. 14172 - 14173
Main Authors Tenn, William J, Young, Kenneth J. H, Bhalla, Gaurav, Oxgaard, Jonas, Goddard, William A, Periana, Roy A
Format Journal Article
LanguageEnglish
Published Washington, DC American Chemical Society 19.10.2005
Subjects
Benzene - chemistry
Catalysis
Chemistry
Exact sciences and technology
Inorganic chemistry and origins of life
Iridium - chemistry
Kinetics and mechanism of reactions
Methanol - chemistry
Molecular Conformation
Organometallic Compounds - chemical synthesis
Organometallic Compounds - chemistry
Oxidation-Reduction
Oxygen - chemistry
Nitrogen heterocycle
Benzene derivatives
Organic ligand
Transition metal Complexes
Experimental study
Iridium Complexes
Chemical activation
Acetylacetone
Alkoxy complex
Pyridine
Complexes Mixed
Platinoid Complexes
Chemical reactivity
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Summary:A thermally and air stable O-donor, iridium−methoxo complex is reported that undergoes stoichiometric, intermolecular C−H activation of benzene with co-generation of methanol and the iridium−phenyl complex.
Bibliography:ark:/67375/TPS-Z5852C5C-P
istex:75A14CCE54E98424A720898F83F427DFD36D5D1C
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0002-7863
1520-5126
DOI:10.1021/ja051497l