Dual-Reagent Catalysis within Ir−Sn Domain: Highly Selective Alkylation of Arenes and Heteroarenes with Aromatic Aldehydes
Reactions of arenes and heteroarenes with aromatic aldehydes proceeded smoothly in the presence of a catalytic combination of [Ir(COD)Cl]2−SnCl4 to afford the corresponding triarylmethane derivatives (TRAMs) in high yields. This 100% TRAM selective transformation is clean and eliminates the use of a...
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| Published in | Journal of organic chemistry Vol. 72; no. 8; pp. 3100 - 3103 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
WASHINGTON
American Chemical Society
13.04.2007
Amer Chemical Soc |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Reactions of arenes and heteroarenes with aromatic aldehydes proceeded smoothly in the presence of a catalytic combination of [Ir(COD)Cl]2−SnCl4 to afford the corresponding triarylmethane derivatives (TRAMs) in high yields. This 100% TRAM selective transformation is clean and eliminates the use of acid systems. |
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| AbstractList | Reactions of arenes and heteroarenes with aromatic aldehydes proceeded smoothly in the presence of a catalytic combination of [Ir(COD)Cl]2-SnCl4 to afford the corresponding triarylmethane derivatives (TRAMs) in high yields. This 100% TRAM selective transformation is clean and eliminates the use of acid systems. Reactions of arenes and heteroarenes with aromatic aldehydes proceeded smoothly in the presence of a catalytic combination of [Ir(COD)Cl]2-SnCl4 to afford the corresponding triarylmethane derivatives (TRAMs) in high yields. This 100% TRAM selective transformation is clean and eliminates the use of acid systems.Reactions of arenes and heteroarenes with aromatic aldehydes proceeded smoothly in the presence of a catalytic combination of [Ir(COD)Cl]2-SnCl4 to afford the corresponding triarylmethane derivatives (TRAMs) in high yields. This 100% TRAM selective transformation is clean and eliminates the use of acid systems. Reactions of arenes and heteroarenes with aromatic aldehydes proceeded smoothly in the presence of a catalytic combination of [Ir(COD)Cl]2−SnCl4 to afford the corresponding triarylmethane derivatives (TRAMs) in high yields. This 100% TRAM selective transformation is clean and eliminates the use of acid systems. |
| Author | Podder, Susmita Roy, Ujjal Kanti Choudhury, Joyanta Roy, Sujit |
| Author_xml | – sequence: 1 givenname: Susmita surname: Podder fullname: Podder, Susmita – sequence: 2 givenname: Joyanta surname: Choudhury fullname: Choudhury, Joyanta – sequence: 3 givenname: Ujjal Kanti surname: Roy fullname: Roy, Ujjal Kanti – sequence: 4 givenname: Sujit surname: Roy fullname: Roy, Sujit |
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| Keywords | ALCOHOLS GOLD(III) CHLORIDE FRIEDEL-CRAFTS ALKYLATION EFFICIENT Catalytic reaction Transition element complexes Tin compound Iridium complex Selectivity Aldehyde Alkylation Platinoid Complexes Aromatic compound Catalysis Platinoid Tin IV Chlorides Heterocyclic compound |
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| Snippet | Reactions of arenes and heteroarenes with aromatic aldehydes proceeded smoothly in the presence of a catalytic combination of [Ir(COD)Cl]2−SnCl4 to afford the... Reactions of arenes and heteroarenes with aromatic aldehydes proceeded smoothly in the presence of a catalytic combination of [Ir(COD)Cl](2)-SnCl4 to afford... Reactions of arenes and heteroarenes with aromatic aldehydes proceeded smoothly in the presence of a catalytic combination of [Ir(COD)Cl]2-SnCl4 to afford the... |
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| SubjectTerms | Aldehydes - chemistry Alkylation Benzene Derivatives - chemistry Catalysis Catalysts: preparations and properties Chemistry Chemistry, Organic Exact sciences and technology General and physical chemistry Iridium - chemistry Molecular Structure Physical Sciences Science & Technology Stereoisomerism Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry Tin - chemistry |
| Title | Dual-Reagent Catalysis within Ir−Sn Domain: Highly Selective Alkylation of Arenes and Heteroarenes with Aromatic Aldehydes |
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