Organic Functionalization of 3C-SiC Surfaces

• Published in: ACS applied materials & interfaces Vol. 5; no. 4; pp. 1393 - 1399
• Main Authors: Schoell, Sebastian J, Sachsenhauser, Matthias, Oliveros, Alexandra, Howgate, John, Stutzmann, Martin, Brandt, Martin S, Frewin, Christopher L, Saddow, Stephen E, Sharp, Ian D
• Format: Journal Article
• Language: English
• Published: United States American Chemical Society 27.02.2013
• Subjects: functionalization; surface photovoltage; monolayer; work function; XPS; silicon carbide
• ISSN: 1944-8244; 1944-8252
• DOI: 10.1021/am302786n

We demonstrate the functionalization of n-type (100) and (111) 3C-SiC surfaces with organosilanes. Self-assembled monolayers (SAMs) of amino-propyldiethoxymethylsilane (APDEMS) and octadecyltrimethoxysilane (ODTMS) are formed via wet chemical processing techniques. Their structural, chemical, and electrical properties are investigated using static water contact angle measurements, atomic force microscopy, and X-ray photoelectron spectroscopy, revealing that the organic layers are smooth and densely packed. Furthermore, combined contact potential difference and surface photovoltage measurements demonstrate that the heterostructure functionality and surface potential can be tuned by utilizing different organosilane precursor molecules. Molecular dipoles are observed to significantly affect the work functions of the modified surfaces. Furthermore, the magnitude of the surface band bending is reduced following reaction of the hydroxylated surfaces with organosilanes, indicating that partial passivation of electrically active surface states is achieved. Micropatterning of organic layers is demonstrated by lithographically defined oxidation of organosilane-derived monolayers in an oxygen plasma, followed by visualization of resulting changes of the local wettability, as well as fluorescence microscopy following immobilization of fluorescently labeled BSA protein.