Fe–P: A New Class of Electroactive Catalyst for Oxygen Reduction Reaction

It has been long thought that Fe–N–C structure, where Fe is bonded with an electronegative heteroatom N, plays a key role as nonprecious metal catalyst for oxygen reduction reaction (ORR) in fuel cells. However, electrocatalytic activity of Fe bonded with electropositive heteroatom P has never been...

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Published inJournal of the American Chemical Society Vol. 137; no. 9; pp. 3165 - 3168
Main Authors Singh, Kiran Pal, Bae, Eun Jin, Yu, Jong-Sung
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 11.03.2015
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Summary:It has been long thought that Fe–N–C structure, where Fe is bonded with an electronegative heteroatom N, plays a key role as nonprecious metal catalyst for oxygen reduction reaction (ORR) in fuel cells. However, electrocatalytic activity of Fe bonded with electropositive heteroatom P has never been considered for ORR. Herein we report the electrocatalytic activity for ORR of new Fe–P–C.
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ISSN:0002-7863
1520-5126
DOI:10.1021/ja511759u