A {Co32} Nanosphere Supported by p-tert-Butylthiacalix[4]arene

Calixarene-capped Co32 clusters are constructed by a sodalite CoII 24 cage and an encapsulated CoIII 8 cube. The spherical units are arranged into three isomeric structures, two of which are stacked by the bcc lattices and the third of which is assembled by the cubic closest packing of the spherical...

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Published inJournal of the American Chemical Society Vol. 131; no. 33; pp. 11650 - 11651
Main Authors Bi, Yanfeng, Wang, Xiu-Teng, Liao, Wuping, Wang, Xiaofei, Wang, Xinwu, Zhang, Hongjie, Gao, Song
Format Journal Article
LanguageEnglish
Published United States American Chemical Society 26.08.2009
Subjects
Cobalt - chemistry
Isomerism
Magnetics
Nanospheres - chemistry
Organometallic Compounds - chemistry
Phenols - chemistry
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Summary:Calixarene-capped Co32 clusters are constructed by a sodalite CoII 24 cage and an encapsulated CoIII 8 cube. The spherical units are arranged into three isomeric structures, two of which are stacked by the bcc lattices and the third of which is assembled by the cubic closest packing of the spherical units.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0002-7863
1520-5126
DOI:10.1021/ja9034939