A {Co32} Nanosphere Supported by p-tert-Butylthiacalix[4]arene
Calixarene-capped Co32 clusters are constructed by a sodalite CoII 24 cage and an encapsulated CoIII 8 cube. The spherical units are arranged into three isomeric structures, two of which are stacked by the bcc lattices and the third of which is assembled by the cubic closest packing of the spherical...
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Published in | Journal of the American Chemical Society Vol. 131; no. 33; pp. 11650 - 11651 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
Published |
United States
American Chemical Society
26.08.2009
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Subjects | |
Online Access | Get full text |
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Summary: | Calixarene-capped Co32 clusters are constructed by a sodalite CoII 24 cage and an encapsulated CoIII 8 cube. The spherical units are arranged into three isomeric structures, two of which are stacked by the bcc lattices and the third of which is assembled by the cubic closest packing of the spherical units. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0002-7863 1520-5126 |
DOI: | 10.1021/ja9034939 |