Coexistence of Magnetic and Electric Orderings in the Metal–Formate Frameworks of [NH4][M(HCOO)3]
A family of three-dimensional chiral metal–formate frameworks of [NH4][M(HCOO)3 ] (M = Mn, Fe, Co, Ni, and Zn) displays paraelectric to ferroelectric phase transitions between 191 and 254 K, triggered by disorder–order transitions of NH4 + cations and their displacement within the framework channels...
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Published in | Journal of the American Chemical Society Vol. 133; no. 38; pp. 14948 - 14951 |
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Main Authors | , , , , , , , , |
Format | Journal Article |
Language | English |
Published |
United States
American Chemical Society
28.09.2011
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Subjects | |
Online Access | Get full text |
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Summary: | A family of three-dimensional chiral metal–formate frameworks of [NH4][M(HCOO)3 ] (M = Mn, Fe, Co, Ni, and Zn) displays paraelectric to ferroelectric phase transitions between 191 and 254 K, triggered by disorder–order transitions of NH4 + cations and their displacement within the framework channels, combined with spin-canted antiferromagnetic ordering within 8–30 K for the magnetic members, providing a new class of metal–organic frameworks showing the coexistence of magnetic and electric orderings. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 0002-7863 1520-5126 |
DOI: | 10.1021/ja206891q |