Nonclassical Active Site for Enhanced Gas Sorption in Porous Coordination Polymer

Gas sorption experiments and grand canonical Monte Carlo simulations for two isostructural microporous metal azolate frameworks show that even partially exposed uncoordinated nitrogens can effectively increase gas binding affinity and overcome the pore size confinement effect.

Saved in:
Bibliographic Details
Published inJournal of the American Chemical Society Vol. 132; no. 19; pp. 6654 - 6656
Main Authors Lin, Jian-Bin, Zhang, Jie-Peng, Chen, Xiao-Ming
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 19.05.2010
Amer Chemical Soc
Subjects
Adsorption
Chemistry
Chemistry, Multidisciplinary
Gases - chemistry
Models, Molecular
Molecular Conformation
Monte Carlo Method
Organometallic Compounds - chemistry
Physical Sciences
Polymers - chemistry
Porosity
Science & Technology
Triazoles - chemistry
STORAGE
CO2
METAL-ORGANIC FRAMEWORK
HYDROGEN ADSORPTION
H-2 ADSORPTION
IMIDAZOLATE
SEPARATION
HIGH-CAPACITY
CARBON-DIOXIDE
MICROPORES
Online AccessGet full text

Cover

More Information
Summary:Gas sorption experiments and grand canonical Monte Carlo simulations for two isostructural microporous metal azolate frameworks show that even partially exposed uncoordinated nitrogens can effectively increase gas binding affinity and overcome the pore size confinement effect.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0002-7863
1520-5126
1520-5126
DOI:10.1021/ja1009635