Rational Design of a Highly Reactive Ratiometric Fluorescent Probe for Cyanide

A novel highly reactive ratiometric fluorescent cyanide probe was judiciously designed based on 2-formylacrylonitrile moiety as a new cyanide reaction site. A DFT study was conducted to rationalize the extremely high reactivity nature of the ratiometric fluorescent cyanide probe.

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Published inOrganic letters Vol. 13; no. 14; pp. 3730 - 3733
Main Authors Yuan, Lin, Lin, Weiying, Yang, Yueting, Song, Jizeng, Wang, Jiaoliang
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 15.07.2011
Amer Chemical Soc
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Abstract A novel highly reactive ratiometric fluorescent cyanide probe was judiciously designed based on 2-formylacrylonitrile moiety as a new cyanide reaction site. A DFT study was conducted to rationalize the extremely high reactivity nature of the ratiometric fluorescent cyanide probe.
AbstractList A novel highly reactive ratiometric fluorescent cyanide probe was judiciously designed based on 2-formylacrylonitrile moiety as a new cyanide reaction site. A DFT study was conducted to rationalize the extremely high reactivity nature of the ratiometric fluorescent cyanide probe.
Author Wang, Jiaoliang
Yang, Yueting
Yuan, Lin
Lin, Weiying
Song, Jizeng
AuthorAffiliation Hunan University
AuthorAffiliation_xml – name: Hunan University
Author_xml – sequence: 1
  givenname: Lin
  surname: Yuan
  fullname: Yuan, Lin
– sequence: 2
  givenname: Weiying
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  surname: Song
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– sequence: 5
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  surname: Wang
  fullname: Wang, Jiaoliang
BackLink https://www.ncbi.nlm.nih.gov/pubmed/21696129$$D View this record in MEDLINE/PubMed
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Snippet A novel highly reactive ratiometric fluorescent cyanide probe was judiciously designed based on 2-formylacrylonitrile moiety as a new cyanide reaction site. A...
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SubjectTerms Chemistry
Chemistry, Organic
Fluorescent Dyes - chemistry
Molecular Conformation
Molecular Structure
Nitriles - analysis
Nitriles - chemistry
Physical Sciences
Science & Technology
Spectrometry, Fluorescence
Title Rational Design of a Highly Reactive Ratiometric Fluorescent Probe for Cyanide
URI http://dx.doi.org/10.1021/ol2013928
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