Rational Design of a Highly Reactive Ratiometric Fluorescent Probe for Cyanide

A novel highly reactive ratiometric fluorescent cyanide probe was judiciously designed based on 2-formylacrylonitrile moiety as a new cyanide reaction site. A DFT study was conducted to rationalize the extremely high reactivity nature of the ratiometric fluorescent cyanide probe.

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Bibliographic Details
Published inOrganic letters Vol. 13; no. 14; pp. 3730 - 3733
Main Authors Yuan, Lin, Lin, Weiying, Yang, Yueting, Song, Jizeng, Wang, Jiaoliang
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 15.07.2011
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Fluorescent Dyes - chemistry
Molecular Conformation
Molecular Structure
Nitriles - analysis
Nitriles - chemistry
Physical Sciences
Science & Technology
Spectrometry, Fluorescence
SENSORS
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Summary:A novel highly reactive ratiometric fluorescent cyanide probe was judiciously designed based on 2-formylacrylonitrile moiety as a new cyanide reaction site. A DFT study was conducted to rationalize the extremely high reactivity nature of the ratiometric fluorescent cyanide probe.
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol2013928