Ruthenium-Catalyzed Oxidative C–H Bond Olefination of N-Methoxybenzamides Using an Oxidizing Directing Group

Ruthenium-catalyzed oxidative C–H bond olefination of N-methoxybenzamides using an oxidizing directing group with a broad substrate scope is reported. The reactions of N-methoxybenzamides with acrylates in MeOH and styrene (or norbornadiene) in CF3CH2OH afforded two types of products.

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Bibliographic Details
Published inOrganic letters Vol. 14; no. 3; pp. 736 - 739
Main Authors Li, Bin, Ma, Jianfeng, Wang, Nuancheng, Feng, Huiliang, Xu, Shansheng, Wang, Baiquan
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 03.02.2012
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
FUNCTIONALIZATION
ACTIVATION
DIRECT ARYLATION
O BOND
HETEROCYCLES
ARENES
REACTIVITY
METAL
ISOQUINOLONE SYNTHESIS
ALKENYLATION
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Summary:Ruthenium-catalyzed oxidative C–H bond olefination of N-methoxybenzamides using an oxidizing directing group with a broad substrate scope is reported. The reactions of N-methoxybenzamides with acrylates in MeOH and styrene (or norbornadiene) in CF3CH2OH afforded two types of products.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1523-7060
1523-7052
DOI:10.1021/ol2032575