Aminocarbonylation of Aryl Halides Using a Nickel Phosphite Catalytic System

The nickel and phosphite catalytic system with sodium methoxide enables a very efficient aminocarbonylation reaction to be performed between aryl iodides or bromides and N,N-dimethylformamide (DMF). Phosphite ligand 1, which is very stable to air and moisture and, furthermore, inexpensive, afforded...

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Bibliographic Details
Published inOrganic letters Vol. 9; no. 22; pp. 4615 - 4618
Main Authors Ju, Jinhun, Jeong, Miso, Moon, Jeongju, Jung, Hyun Min, Lee, Sunwoo
Format Journal Article
LanguageEnglish
Published WASHINGTON American Chemical Society 25.10.2007
Amer Chemical Soc
Subjects
Chemistry
Chemistry, Organic
Physical Sciences
Science & Technology
CHLORIDES
IODIDES
DIRECT CARBAMOYLATION
CARBONYLATION
CARBON-MONOXIDE SOURCE
BROMIDES
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Summary:The nickel and phosphite catalytic system with sodium methoxide enables a very efficient aminocarbonylation reaction to be performed between aryl iodides or bromides and N,N-dimethylformamide (DMF). Phosphite ligand 1, which is very stable to air and moisture and, furthermore, inexpensive, afforded the highest reaction yield.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1523-7060
1523-7052
DOI:10.1021/ol702058e